Size-dependent luminescence of small palladium particles

被引:29
作者
Adelt, M [1 ]
Nepijko, S [1 ]
Drachsel, W [1 ]
Freund, HJ [1 ]
机构
[1] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany
关键词
D O I
10.1016/S0009-2614(98)00620-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report cathodoluminescence spectra of small Pd clusters of various size deposited on a thin, well-ordered oxide film. The size distribution of the deposited metal aggregates can be chosen and deliberately varied. The luminescence spectra vary characteristically as a function of the variation of particle size. The resonance energy at the highest luminescence energy with decreasing average particle size vary as expected for electronic states in a quantum confined metal particle. For an average aggregate size of 10 Angstrom the luminescence is maximum. (C) 1998 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:425 / 432
页数:8
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