Efficiency enhanced electrolysis-based tritium continuous monitor

被引：3
作者：
Bae, Jun Woo [1 ]
Kang, Ki Joon [1 ]
Kim, Hee Reyoung [1 ]
机构：
[1] Ulsan Natl Inst Sci & Technol, Dept Nucl Engn, Ulsan, South Korea
来源：
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY | 2019年 / 322卷 / 03期
基金：
新加坡国家研究基金会;
关键词：
Proton exchange membrane; Electrolysis; Tritium; Continuous monitoring; Fractionation factor; SCINTILLATION-COUNTER; TRITIATED-WATER;
D O I：
10.1007/s10967-019-06836-8
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Developing an online monitoring system becomes useful for continuously detection of tritium in water. A plastic scintillator chamber was used to tritium detection in hydrogen gas produced by a proton exchange membrane electrolysis cell. The fractionation factor (proton selectivity) was estimated as being of 5.41 +/- 0.20, and detection efficiency of the plastic scintillator chamber was 4.25 +/- 0.22%. For liquid samples, the minimum detectable activity of the developed system was estimated as 655 kBq L-1. Using this online technique for tritium monitoring based on electrolysis is expected to be useful for analysis of large tritiated water bearing samples.
引用
收藏
页码：1323 / 1329
页数：7
相关论文
共 22 条
  • [1] Analytical modelling and experimental validation of proton exchange membrane electrolyser for hydrogen production
    Aouali, F. Z.
    Becherif, M.
    Ramadan, H. S.
    Emziane, M.
    Khellaf, A.
    Mohammedi, K.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2017, 42 (02) : 1366 - 1374
  • [2] Development of continuous inflow tritium measurement in water technology using electrolysis and a plastic scintillator
    Bae, Jun Woo
    Lee, UkJae
    Kim, Hee Reyoung
    [J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2017, 314 (02) : 689 - 694
  • [3] Dispersion and removal characteristics of tritium originated from nuclear power plants in the atmosphere
    Chae, Jung-Seok
    Kim, Guebuem
    [J]. JOURNAL OF ENVIRONMENTAL RADIOACTIVITY, 2018, 192 : 524 - 531
  • [4] Pulse Shape Discrimination in Polysiloxane-Based Liquid Scintillator
    Dalla Palma, Matteo
    Marchi, Tommaso
    Carturan, Sara
    Checchia, Caterina
    Collazuol, Gianmaria
    Gramegna, Fabiana
    Daldosso, Nicola
    Paterlini, Veronica
    Quaranta, Alberto
    Cinausero, Marco
    Degerlier, Meltem
    [J]. IEEE TRANSACTIONS ON NUCLEAR SCIENCE, 2016, 63 (03) : 1608 - 1615
  • [5] Prototype apparatus for the measurement of tritium in expired air using plastic scintillator pellets
    Furuta, Etsuko
    Ito, Takeshi
    [J]. APPLIED RADIATION AND ISOTOPES, 2018, 132 : 151 - 156
  • [6] Measurement of tritium with plastic scintillators in large vials of a low background liquid scintillation counter: an organic waste-less method
    Furuta, Etsuko
    Kato, Yuka
    Fujisawa, Shinji
    [J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2017, 314 (02) : 701 - 708
  • [7] A plastic scintillation counter prototype
    Furuta, Etsuko
    Kawano, Takao
    [J]. APPLIED RADIATION AND ISOTOPES, 2015, 104 : 175 - 180
  • [8] An online method to measure tritium production rate of fusion -fission hybrid reactor in CAEP
    He Tie
    Wang Xinhua
    An Li
    Yang Jian
    Zheng Pu
    [J]. FUSION ENGINEERING AND DESIGN, 2018, 137 : 43 - 47
  • [9] Sampling tritiated water vapor from the atmosphere by an active system using silica gel
    Herranz, M.
    Alegria, N.
    Idoeta, R.
    Legarda, F.
    [J]. RADIATION PHYSICS AND CHEMISTRY, 2011, 80 (11) : 1172 - 1177
  • [10] Tritium concentration analysis in atmospheric precipitation in Serbia
    Jankovic, Marija M.
    Jankovic, Bojan Z.
    Todorovic, Dragana J.
    Ignjatovic, Ljubisa M.
    [J]. JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING, 2012, 47 (05): : 669 - 674
123