Synthesis and crystal structure of complex [Cd(NIT4Py)2][Au(CN)2]2

被引：0
|
作者：
Wang Shu-Ping [1 ]
Zhang Xu-Hong [1 ]
Yang Shu-Tao [1 ]
机构：
[1] Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050016, Peoples R China
来源：
CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 23卷 / 06期
关键词：
nitronyl nitroxide radical; eadmium(II) complex; dicyanoaurate(I); crystal structure; one-dimensional;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A Cd(II)-nitronyl nitroxide radical complex with dicyanoaurate(I) bridges [Cd(NIT4Py)(2)][Au(CN)(2)](2), was synthesized and characterized by elemental analyses, IR spectrum and X-ray diffraction single-crystal structure analysis. Crystal data for the complex: triclinic, space group P (1) over bar, a=0.720 9(11) nm, b =0.960 3(15) nm, c = 1.284(2) nm, alpha=75.38(2)degrees, beta=85.46(2)degrees, gamma=68.38(2)degrees, V=0.800(2) nm(3), Z=l, and R-1, [I > 2 sigma(I)]=0.055 8. The title complex consists of infinite one-dimensional chains of [Cd(NIT4Py)2][Au(CN)(2)](2), in which [Cd(NIT4Py)(2)] moieties are connected by [Au(CN)(2)](-)mu(2)-bridging ligands. Each cadmium(II) ion is six-coordinated in a distorted and centrosymmetric octahedral environment. CCDC: 258357.
引用
收藏
页码：1075 / 1077
页数：3
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