A hydrophilic matrix for boron isolation: Monodisperse-porous poly(glycidyl methacrylate-co-ethylene dimethacrylate) particles carrying diol functionality

被引:19
|
作者
Samatya, Saba [1 ]
Kabay, Nalan [2 ]
Tuncel, Ali [1 ]
机构
[1] Hacettepe Univ, Dept Chem Engn, TR-06532 Ankara, Turkey
[2] Ege Univ, Dept Chem Engn, Izmir, Turkey
关键词
Boron; Boron-selective sorbents; Modified seeded polymerization; Monodisperse-porous particles; Adsorption; ION-EXCHANGE; DISPERSION POLYMERIZATION; WASTE-WATER; BORIC-ACID; REMOVAL; NANOPARTICLES; RECOVERY; CARBON; RESINS;
D O I
10.1016/j.reactfunctpolym.2010.05.004
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
The novel chelating adsorbent has been synthesized by functionalization of monodisperse-porous poly(glycidyl methacrylate-co-ethylene dimethacrylate) particles with N-methylglucamine (NMDG) as a boron selective ligand. The resulting resin can adsorb boron in almost all pH range (pH 4-10) and its maximum capacity is ca. 12 mg/g. The adsorption behavior of poly(GMA-co-EDM)NMDG resin obeyed Langmuir isotherm well. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:555 / 562
页数:8
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