Unusually low pour point of fatty acid methyl esters with low saturated fatty acid content

被引:9
作者
Nie, Jieyu [1 ]
Wang, Sunmin [2 ]
Emami, Shahram [3 ]
Falk, Kevin [4 ]
Shen, Jianheng [3 ]
Reaney, Martin J. T. [3 ,5 ]
机构
[1] Univ Saskatchewan, Dept Food & Bioprod Sci, Saskatoon, SK, Canada
[2] Bioriginal Food & Sci Corp, Saskatoon, SK, Canada
[3] Univ Saskatchewan, Dept Plant Sci, Saskatoon, SK S7N 5A8, Canada
[4] Agr & Agri Food Canada, Saskatoon, SK, Canada
[5] Jinan Univ, Dept Food Sci & Engn, Guangzhou, Guangdong, Peoples R China
基金
加拿大自然科学与工程研究理事会;
关键词
Fatty acid profile; Fatty acid methyl ester; Vegetable oil; Cold fluidity; Cloud point; Pour point; Oxidative stability; OXIDATIVE STABILITY; THERMAL-PROPERTIES; EUTECTIC MIXTURES; BIODIESEL; TEMPERATURE;
D O I
10.1002/ejlt.201400500
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
Many oilseeds grown in Canada have unusual fatty acid profiles including Cruciferous oilseed varieties that have very low levels (<3%) of saturated fatty acid. In this study oil samples were obtained from five cultivars of Brassica rapa L., seven cultivars of Brassica napus L. and five cultivars from other oilseeds species namely Brassica juncea L., Sinapis alba L., Camelina sativa L. and Linum usitatissimum L. The fatty acid profile, cloud point (CP) and pour point (PP) were determined for each oil sample. Fatty acid methyl esters (FAME) were synthesized from each oil sample. The saturated fatty acid content was highly correlated (R-2 = 0.93) with PP in methyl esters prepared from Brassica sp. oils. In addition, we identified three publications where PP was measured on fatty acid methyl esters and found that the correlation of PP with saturated fat content was consistent with data presented herein. Since B. rapa oil exhibited superior low temperature properties, it was chosen for further studies of oxidative stability. B. rapa cultivars, with less than 3.5% saturated fat and less than 20% polyunsaturated fat, can be an excellent feedstock for production of oils with improved cold fluidity and oxidative stability.
引用
收藏
页码:1486 / 1494
页数:9
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