Oxidative Kinetic Self-Sorting of a Dynamic Imine Library

被引：89
|
作者：
Osowska, Karolina [1 ]
Miljanic, Ognjen S. [1 ]
机构：
[1] Univ Houston, Dept Chem, Houston, TX 77204 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2011年 / 133卷 / 04期
关键词：
EXTENSIONS; SYSTEMS;
D O I：
10.1021/ja109754t
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Dynamic libraries of [n x n] imine components spontaneously simplify during a slow oxidation reaction to produce only n discrete products. The selectivity of this self-sorting process is a consequence of different oxidation rates for various imines, while the dynamic nature of the library enables self-sorting to proceed with high efficiency.
引用
收藏
页码：724 / 727
页数：4
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