Selective aerobic oxidation of sulfides to sulfoxides catalyzed by coenzyme NAD+ models

被引：16

作者：

Xu, Hua-Jian ^{[1
,2
]}

Lin, Yi-Cheng ^{[1
]}

Wan, Xin ^{[1
]}

Yang, Chun-Yan ^{[1
]}

Feng, Yi-Si ^{[1
,2
]}

机构：

[1] Hefei Univ Technol, Sch Chem Engn, Hefei 230009, Peoples R China

[2] Anhui Key Lab Controllable Chem React & Mat Chem, Hefei 230009, Peoples R China

来源：

TETRAHEDRON | 2010年 / 66卷 / 46期

基金：

中国国家自然科学基金;

关键词：

MOLECULAR-OXYGEN; ELECTRON-TRANSFER; SINGLET-OXYGEN; CHEMOSELECTIVE OXIDATION; PHOTOCATALYTIC OXIDATION; ASYMMETRIC-SYNTHESIS; CHIRAL LIGANDS; BENZYL ALCOHOL; EFFICIENT; 10-METHYLACRIDINIUM;

D O I：

10.1016/j.tet.2010.09.076

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Coenzyme NAD(+) models can be applied in the photooxygenation of sulfides to sulfoxides as organocatalysts at room temperature. A series of sulfoxides are synthesized easily with this protocol and the possible mechanism is discussed. This procedure provides a reliable approach to the clean production of useful sulfoxides in synthetic chemistry. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：8823 / 8827

页数：5

共 68 条

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