Facile Access to Novel [60]Fullerenyl Diethers and [60]Fullerene-Sugar Conjugates via Annulation of Diol Moieties

被引：31

作者：

Zhai, Wen-Qiang ^{[1
,2
]}

Jiang, Sheng-Peng ^{[1
,2
]}

Peng, Ru-Fang ^{[3
]}

Jin, Bo ^{[3
]}

Wang, Guan-Wu ^{[1
,2
,3
]}

机构：

[1] Univ Sci & Technol China, CAS Key Lab Soft Matter Chem, iChEM Collaborat Innovat Ctr Chem Energy Mat, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China

[2] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China

[3] Southwest Univ Sci & Technol, State Key Lab Cultivat Base Nonmet Composites & F, Mianyang 621010, Sichuan, Peoples R China

来源：

ORGANIC LETTERS | 2015年 / 17卷 / 08期

基金：

中国国家自然科学基金;

关键词：

PERCHLORATE-MEDIATED SYNTHESIS; CYCLOADDITION; FULLERENES; HETEROANNULATION; SULFONAMIDES; DERIVATIVES; CHEMISTRY; CHLORIDE; ESTERS; C-60;

D O I：

10.1021/acs.orglett.5b00536

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A general and facile annulation of various diol motifs to [60]fullerene has been developed. This protocol can afford not only 6- to 10-membered-ring fullerenyl diethers in one step from simple acyclic diols but also directly couple [60]fullerene with a variety of structurally diverse sugars. The [60]fullerene-sugar conjugates formed do not require any linker moiety and maintain their inherent structural integrity. The electrochemistry of the fullerenyl diethers and [60]fullerene-sugar conjugates has also been investigated.

引用

页码：1862 / 1865

页数：4

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