Chemical fixation of carbon dioxide by NaI/PPh3/PhOH

被引：237

作者：

Huang, JW ^{[1
]}

Shi, M ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 68卷 / 17期

关键词：

D O I：

10.1021/jo0348221

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In the presence of catalytic amounts of sodium iodide, triphenylphosphine, and phenol, carbon dioxide can efficiently react with epoxides to give the corresponding five-membered cyclic carbonates in high yields. The mechanism of this reaction was disclosed by P-31 NMR spectroscopic data and deuterium labeling experiments.

引用

页码：6705 / 6709

页数：5

共 49 条

[1] ACTIVATION OF CARBON-DIOXIDE WITH ALUMINUM PORPHYRIN AND REACTION WITH EPOXIDE - STUDIES ON (TETRAPHENYLPORPHINATO)ALUMINUM ALKOXIDE HAVING A LONG OXYALKYLENE CHAIN AS THE ALKOXIDE GROUP [J].

AIDA, T ;

INOUE, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (05) :1304-1309

[2] CHEMICAL SYNTHESIS OF OLIGONUCLEOTIDES [J].

AMARNATH, V ;

BROOM, AD .

CHEMICAL REVIEWS, 1977, 77 (02) :183-217

[3]

Anastas P.T., 1996, GREEN CHEM DESIGNING, DOI [10.1021/bk-1996-0626, DOI 10.1021/BK-1996-0626]

[4]

[Anonymous], ORGANIC BIOORGANIC C

[5] CARBONATE FORMATION FROM OXIRANES AND CARBON-DIOXIDE CATALYZED BY ORGANOTIN HALIDE-TETRAALKYLPHOSPHONIUM HALIDE-COMPLEXES [J].

BABA, A ;

NOZAKI, T ;

MATSUDA, H .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1987, 60 (04) :1552-1554

[6] STEREOCHEMISTRY OF COPPER-CATALYZED AND NICKEL-CATALYZED INSERTION OF CARBON-DIOXIDE INTO EPOXIDES - A MICROWAVE STUDY [J].

BACKVALL, JE ;

KARLSSON, O ;

LJUNGGREN, SO .

TETRAHEDRON LETTERS, 1980, 21 (51) :4985-4988

[7]

Behr A., 1988, CARBON DIOXIDE ACTIV

[8]

Brindopke G., 1987, German Patent, Patent No. [DE 3529263, 3529263]

[9] Cyclic carbonate formation from carbon dioxide and oxiranes in tetrabutylammonium halides as solvents and catalysts [J].

Caló, V ;

Nacci, A ;

Monopoli, A ;

Fanizzi, A .

ORGANIC LETTERS, 2002, 4 (15) :2561-2563

[10] Green Chemistry: challenges and opportunities [J].

Clark, JH .

GREEN CHEMISTRY, 1999, 1 (01) :1-8

← 1 2 3 4 5 →