Direct Identification of the Conducting Channels in a Functioning Memristive Device

被引:300
作者
Strachan, John Paul [1 ]
Pickett, Matthew D. [1 ]
Yang, J. Joshua [1 ]
Aloni, Shaul [2 ]
Kilcoyne, A. L. David [3 ]
Medeiros-Ribeiro, Gilberto [1 ]
Williams, R. Stanley [1 ]
机构
[1] Hewlett Packard Labs, Informat & Quantum Syst Lab, Palo Alto, CA 94304 USA
[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Mol Foundry, Berkeley, CA 94720 USA
[3] Univ Calif Berkeley, Lawrence Berkeley Lab, Adv Light Source, Berkeley, CA 94720 USA
关键词
X-RAY-ABSORPTION; RESISTIVE SWITCHING MEMORIES; RESISTANCE; TITANIUM; SPECTRA; SRTIO3; FILMS; TIO2;
D O I
10.1002/adma.201000186
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Titanium dioxide memristive devices have been non-destructively characterized using X-ray absorption spectromicroscopy and TEM. These techniques allow direct identification of the chemistry and structure of the conducting channel responsible for the bipolar resistance switching seen in these devices. Within the TiO2 matrix, we observe the formation of a Ti4O7 Magneli phase possessing metallic properties and ordered planes of oxygen vacancies.
引用
收藏
页码:3573 / +
页数:6
相关论文
共 34 条
[11]   Coexistence of bipolar and unipolar resistive switching behaviors in a Pt/TiO2/Pt stack [J].
Jeong, Doo Seok ;
Schroeder, Herbert ;
Waser, Rainer .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2007, 10 (08) :G51-G53
[12]   Mechanism for bipolar switching in a Pt/TiO2/Pt resistive switching cell [J].
Jeong, Doo Seok ;
Schroeder, Herbert ;
Waser, Rainer .
PHYSICAL REVIEW B, 2009, 79 (19)
[13]   Microscopic origin of bipolar resistive switching of nanoscale titanium oxide thin films [J].
Jeong, Hu Young ;
Lee, Jeong Yong ;
Choi, Sung-Yool ;
Kim, Jeong Won .
APPLIED PHYSICS LETTERS, 2009, 95 (16)
[14]   Interferometer-controlled scanning transmission X-ray microscopes at the Advanced Light Source [J].
Kilcoyne, ALD ;
Tyliszczak, T ;
Steele, WF ;
Fakra, S ;
Hitchcock, P ;
Franck, K ;
Anderson, E ;
Harteneck, B ;
Rightor, EG ;
Mitchell, GE ;
Hitchcock, AP ;
Yang, L ;
Warwick, T ;
Ade, H .
JOURNAL OF SYNCHROTRON RADIATION, 2003, 10 :125-136
[15]  
Kwon DH, 2010, NAT NANOTECHNOL, V5, P148, DOI [10.1038/NNANO.2009.456, 10.1038/nnano.2009.456]
[16]   Thermodynamics of oxygen defective Magneli phases in rutile: A first-principles study [J].
Liborio, Leandro ;
Harrison, Nicholas .
PHYSICAL REVIEW B, 2008, 77 (10)
[17]   An NEXAFS investigation of the reduction and reoxidation of TiO2(001) [J].
Lusvardi, VS ;
Barteau, MA ;
Chen, JG ;
Eng, J ;
Fruhberger, B ;
Teplyakov, A .
SURFACE SCIENCE, 1998, 397 (1-3) :237-250
[18]   Oxide Interfaces-An Opportunity for Electronics [J].
Mannhart, J. ;
Schlom, D. G. .
SCIENCE, 2010, 327 (5973) :1607-1611
[19]   CRYSTAL STRUCTURE OF TI4O7 - MEMBER OF HOMOLOGOUS SERIES TINO2N-1 [J].
MAREZIO, M ;
DERNIER, PD .
JOURNAL OF SOLID STATE CHEMISTRY, 1971, 3 (03) :340-&
[20]   Materials science - Who wins the nonvolatile memory race? [J].
Meijer, G. I. .
SCIENCE, 2008, 319 (5870) :1625-1626