Improved Bimetallic Cobalt-Manganese Catalysts for Selective Oxidative Cleavage of Morpholine Derivatives

被引：20

作者：

Leonard, David K. ^{[1
]}

Li, Wu ^{[1
]}

Junge, Kathrin ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Catalysis, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

ACS CATALYSIS | 2019年 / 9卷 / 12期

关键词：

manganese; cobalt; oxidation; C-C bond activation; heterocycles; TEREPHTHALIC ACID;

D O I：

10.1021/acscatal.9b03476

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Catalytic methods for the site-selective scission of C(sp(3))-C(sp(3)) bonds remain scarcely explored in contrast to the vast literature on C-C coupling. In view of this, we report a means of oxidative C-C single-bond cleavage in morpholines, made possible by a synergy between cobalt and manganese catalysts using air as a benign oxidant. We demonstrate the synthetic utility of this system with the late-stage oxidative cleavage of Linezolid.

引用

页码：11125 / 11129

页数：9

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