Thienyl and thenyl alkyl disulfides: monomers and polymers

被引：2

作者：

Duchenet, V

Andrieu, CG

Catel, JM

Le Coustumer, G

Penneau, JF

Le Guillanton, G

Hapiot, P

Audebert, P

机构：

[1] Univ Caen, ISMRA, Lab Chim Mol & Thioorgan, CNRS,UMR 6507, F-14050 Caen, France

[2] Univ Catholique Ouest, CNRS, UMR 6501, Lab Electrochim Organ, F-49008 Angers, France

[3] Univ Paris 07, Electrochim Mol Lab, F-75251 Paris, France

[4] Univ Franche Comte, Chim Organ Lab, F-25030 Besancon, France

[5] Ctr Rech EDF, F-77250 Moret Sur Loing, France

来源：

JOURNAL DE CHIMIE PHYSIQUE ET DE PHYSICO-CHIMIE BIOLOGIQUE | 1998年 / 95卷 / 06期

关键词：

thiophene; disulfide; polymerization; passivation;

D O I：

10.1051/jcp:1998253

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Thienyl and thenyl alkyl disulfides are synthesized by reaction between a mercaptan and dialkylazodicarboxylate; the addition of a second mercaptan gives the unsymmetrical disulfide. The cyclic disulfide, dithieno[3,2-c:2',3'-e][1,2] dithiin is obtained from the 2,2'-dibromobithiophene. These thiophene derivatives including a second redox system are potential precursors for polymers. Chemical polymerization affords new materials.

引用

页码：1229 / 1233

页数：5

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