Sandwiched Thin-Film Anode of Chemically Bonded Black Phosphorus/Graphene Hybrid for Lithium-Ion Battery

被引：141
作者：
Liu, Hanwen [1 ]
Zou, Yuqin [2 ]
Tao, Li [1 ]
Ma, Zhaoling [1 ]
Liu, Dongdong [1 ]
Zhou, Peng [1 ]
Liu, Hongbo [1 ]
Wang, Shuangyin [1 ]
机构：
[1] Hunan Univ, Coll Chem & Chem Engn, Prov Hunan Key Lab Graphene Mat & Devices, Coll Mat Sci & Engn,State Key Lab Chem Biosensing, Changsha 410082, Hunan, Peoples R China
[2] Beijing Univ Chem Technol, Coll Energy, Beijing 100029, Peoples R China
来源：
SMALL | 2017年 / 13卷 / 33期
基金：
中国国家自然科学基金;
关键词：
REDUCED GRAPHENE OXIDE; HIGH-PERFORMANCE ANODE; POROUS CARBON; ELECTROCHEMICAL ACTIVITY; DOPED GRAPHENE; HIGH-CAPACITY; PHOSPHORENE; NANOTUBES; ELECTRODE; COMPOSITE;
D O I：
10.1002/smll.201700758
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A facile vacuum filtration method is applied for the first time to construct sandwich-structure anode. Two layers of graphene stacks sandwich a composite of black phosphorus (BP), which not only protect BP from quickly degenerating but also serve as current collector instead of copper foil. The BP composite, reduced graphene oxide coated on BP via chemical bonding, is simply synthesized by solvothermal reaction at 140 degrees C. The sandwiched film anode used for lithium-ion battery exhibits reversible capacities of 1401 mAh g(-1) during the 200th cycle at current density of 100 mA g(-1) indicating superior cycle performance. Besides, this facile vacuum filtration method may also be available for other anode material with well dispersion in N-methyl pyrrolidone (NMP).
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页数：9
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