Uranyl-Promoted Peroxide Generation: Synthesis and Characterization of Three Uranyl Peroxo [(UO2)2(O2)] Complexes

被引：37

作者：

Thangavelu, Sonia G. ^{[1
]}

Cahill, Christopher L. ^{[1
]}

机构：

[1] George Washington Univ, Dept Chem, Washington, DC 20052 USA

来源：

INORGANIC CHEMISTRY | 2015年 / 54卷 / 09期

关键词：

CRYSTAL-STRUCTURES; ORGANIC ASSEMBLIES; LUMINESCENCE; 1ST-PRINCIPLES; DYNAMICS; STUDTITE; NITRATE; ORIGIN; LIGAND; IONS;

D O I：

10.1021/ic502767k

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three novel uranyl(VI) peroxide complexes, [(UO2)(2)(CH3COO)(2)(O-2)(C10H8N2)] (1), [(UO2)(2)(CH3COO)(2)(O-2)(C12H12N2)] (2), and [(UO2)(3)(CH3COO)(4)(O-2) (C15H11N3] (3), have been synthesized and characterized by single-crystal X-ray diffraction, powder X-ray diffraction, and luminescence spectroscopy. Each of these structures feature a [(UO2)(2)(O-2)] dimer with additional coordination by acetate, 2,2'-bipyridine (BP), 5,5'-dimethyl-2,2'-bipyridine (MeBPY), or 2,2':6,2 ''-terpyridine (TPY). Compound 3 consists of an additional uranyl unit functionalized with a TPY donor ligand. The presence of the peroxo ligand in 1-3 is due to in situ generation of peroxide when preparative solutions of 1-3 were exposed to ambient light and/or sunlight.

引用

页码：4208 / 4221

页数：14

共 57 条

[1] Hybrid Uranyl-Carboxyphosphonate Cage Clusters [J].

Adelani, Pius O. ;

Ozga, Michael ;

Wallace, Christine M. ;

Qiu, Jie ;

Szymanowski, Jennifer E. S. ;

Sigmon, Ginger E. ;

Burns, Peter C. .

INORGANIC CHEMISTRY, 2013, 52 (13) :7673-7679

[2]

Akbarzadeh-T N., 2013, RES CHEM INTERMEDIAT, P1

[3] CRYSTAL AND MOLECULAR STRUCTURE OF SODIUM URANYL TRIPEROXIDE [J].

ALCOCK, NW .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (07) :1588-&

[4] ACTINIDE STRUCTURAL STUDIES .7. THE CRYSTAL AND MOLECULAR-STRUCTURES OF (2,2'-BIPYRIDYL)DINITRATODIOXO-URANIUM(VI) AND DINITRATODIOXO-NEPTUNIUM(VI), AND DIACETATO-(2,2'-BIPYRIDYL)DIOXO-URANIUM(VI) AND DIOXO-NEPTUNIUM(VI) [J].

ALCOCK, NW ;

FLANDERS, DJ ;

BROWN, D .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (05) :1001-1007

[5] COMPLETION AND REFINEMENT OF CRYSTAL-STRUCTURES WITH SIR92 [J].

ALTOMARE, A ;

CASCARANO, G ;

GIACOVAZZO, C ;

GUAGLIARDI, A .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1993, 26 (pt 3) :343-350

[6] Uranyl peroxide enhanced nuclear fuel corrosion in seawater [J].

Armstrong, Christopher R. ;

Nyman, May ;

Shvareva, Tatiana ;

Sigmon, Ginger E. ;

Burns, Peter C. ;

Navrotsky, Alexandra .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2012, 109 (06) :1874-1877

[7] Study of uranyl(VI) malonate complexation by time resolved laser-induced fluorescence spectroscopy (TRLFS) [J].

Brachmann, A ;

Geipel, G ;

Bernhard, G ;

Nitsche, H .

RADIOCHIMICA ACTA, 2002, 90 (03) :147-153

[8] New software for searching the Cambridge Structural Database and visualizing crystal structures [J].

Bruno, IJ ;

Cole, JC ;

Edgington, PR ;

Kessler, M ;

Macrae, CF ;

McCabe, P ;

Pearson, J ;

Taylor, R .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2002, 58 :389-397

[9] Structure of a uranyl peroxo complex in aqueous solution from first-principles molecular dynamics simulations [J].

Buehl, Michael ;

Sieffert, Nicolas ;

Wipff, Georges .

DALTON TRANSACTIONS, 2014, 43 (29) :11129-11137

[10] Actinyl peroxide nanospheres [J].

Burns, PC ;

Kubatko, KA ;

Sigmon, G ;

Fryer, BJ ;

Gagnon, JE ;

Antonio, MR ;

Soderholm, L .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (14) :2135-2139

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