Structure characterization of CUCl2-FeCl3-H2SO4 graphite intercalation compounds

被引：0

作者：

Liang, Chong-yun ^{[1
]}

Che, Ren-chao ^{[1
]}

Tian, Huan-fang ^{[1
]}

Shi, Hong-long ^{[1
]}

Li, Jian-qi ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100080, Peoples R China

来源：

CHINESE JOURNAL OF CHEMICAL PHYSICS | 2007年 / 20卷 / 06期

关键词：

CUCl2-FeCl3-H2SO4; graphite intercalation compounds; structure;

D O I：

10.1088/1674-0068/20/06/806-810

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Graphite intercalation compounds with CUCl2-FeCl3-H2SO4 were synthesized via a hydrothermal treatment at 150 degrees C and exfoliation method. The structure and composition of these graphite intercalation compounds were analyzed by means of X-ray diffraction, energy dispersive X-ray and high-resolution transmission electron microscopy. The results demonstrate that the CUCl2-FeCl3-H2SO4 molecules were successfully intercalated into the interlayer of the graphite sheets. The temperature dependence of magnetization was measured from 5 K to 300 K. Two anti ferro magnetic transitions of the graphite intercalation compounds were observed at low temperatures. The critical transition temperatures are estimated to be about 50 and 102 K. The related magnetic properties are discussed briefly.

引用

页码：806 / 810

页数：5

共 34 条

[1] BIINTERCALATION OF ICL INTO A STAGE-5 FECL3 GRAPHITE-INTERCALATION COMPOUND [J].