Magnetocaloric effect of the Gd3-x TbxCo system

被引:8
作者
Guzik, A. [1 ]
Talik, E. [1 ]
Zajdel, P. [1 ]
机构
[1] Univ Silesia, Inst Phys, 75 Pulku Piechoty 1, PL-41500 Chorzow, Poland
关键词
MAGNETIC-PROPERTIES; GD; DY;
D O I
10.1016/j.intermet.2019.106686
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Gd3-xTbxCo compounds with x = 0, 0.25, 0.5, 1, 1.5, 2, 2.5 and 3 were investigated using structural and magnetic methods. The lattice parameters, and the location of 4c and 8d Wyckoff sites occupied by Gd, Tb, and Co atoms, in an Fe3C orthorhombic type of structure, were refined by the Rietveld method. The magnetic ordering temperature changes linearly with Tb content. The magnetocaloric effect (MCE) in Tb3Co at 77 K and a magnetic field of 7 T is equal to -28.8 J/kgK. An inverse MCE observed in GdTb2Co reaches its maximum value of 6.8 J/kgK at 47 K and a magnetic field of 6 T.
引用
收藏
页数:10
相关论文
共 20 条
[1]   High-field magnetization and magnetic structure of Tb3Co [J].
Baranov, N. V. ;
Gubkin, A. F. ;
Vokhmyanin, A. P. ;
Pirogov, A. N. ;
Podlesnyak, A. ;
Keller, L. ;
Mushnikov, N. V. ;
Bartashevich, M. I. .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2007, 19 (32)
[2]   MAGNETIC PHASE-TRANSITIONS IN GD3CO [J].
BARANOV, NV ;
ANDREEV, AV ;
KOZLOV, AI ;
KVASHNIN, GM ;
NAKOTTE, H ;
KATORI, HA ;
GOTO, T .
JOURNAL OF ALLOYS AND COMPOUNDS, 1993, 202 :215-224
[3]   CRYSTAL STRUCTURE OF RARE-EARTH COBALT COMPOUNDS OF TYPE R3CO [J].
BUSCHOW, KHJ ;
VANDERGO.AS .
JOURNAL OF THE LESS-COMMON METALS, 1969, 18 (03) :309-&
[4]  
Carvajal R., 2001, COMMISSION POWDER DI, V26, P12, DOI DOI 10.1007/S00603-013-0527-Z
[5]  
Cullity B. D., 2009, INTRO MAGNETIC MAT, p[48, 115]
[6]   OBSERVATION OF FACE-CENTERED CUBIC GD, TB, DY, HO, ER AND TM IN FORM OF THIN-FILMS AND THEIR OXIDATION [J].
CURZON, AE ;
CHLEBEK, HG .
JOURNAL OF PHYSICS F-METAL PHYSICS, 1973, 3 (01) :1-5
[7]   Broadening of temperature working range in magnetocaloric La(Fe,Co,Si)13- based multicomposite [J].
Gebara, Piotr ;
Pawlik, Piotr .
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS, 2017, 442 :145-151
[8]   Magnetic glassy behaviour coupled with long range non-collinear magnetic order in Tb3Co [J].
Goswami, Srikanta ;
Babu, P. D. ;
Rawat, R. .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2019, 31 (44)
[9]   Comprehensive study of the magnetic phase transitions in Tb3Co combining thermal, magnetic and neutron diffraction measurements [J].
Herrero, A. ;
Oleaga, A. ;
Gubkin, A. F. ;
Frontzek, M. D. ;
Salazar, A. ;
Baranov, N., V .
INTERMETALLICS, 2019, 111
[10]   Large reversible magnetocaloric effect in Tb3Co compound [J].
Li, B. ;
Du, J. ;
Ren, W. J. ;
Hu, W. J. ;
Zhang, Q. ;
Li, D. ;
Zhang, Z. D. .
APPLIED PHYSICS LETTERS, 2008, 92 (24)