Chemical Synthesis of Fully Biomass-Based Poly(butylene succinate) from Inedible-Biomass-Based Furfural and Evaluation of Its Biomass Carbon Ratio

被引：135

作者：

Tachibana, Yuya ^{[1
]}

Masuda, Takashi ^{[1
]}

Funabashi, Masahiro ^{[1
]}

Kunioka, Masao ^{[1
]}

机构：

[1] Natl Inst Adv Ind Sci & Technol, Tsukuba, Ibaraki 3058565, Japan

来源：

BIOMACROMOLECULES | 2010年 / 11卷 / 10期

关键词：

ACCELERATOR MASS-SPECTROMETRY; POLY-EPSILON-CAPROLACTONE; MECHANICAL-PROPERTIES; BIODEGRADABLE POLYESTERS; INTERNATIONAL STANDARD; CONTROLLED COMPOST; BIOBASED CONTENTS; CELLULOSE; POLYCAPROLACTONE; CRYSTALLIZATION;

D O I：

10.1021/bm100820y

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

We have produced fully biomass-based poly(butylene succinate) (PBS) from furfural produced from inedible agricultural cellulosic waste. Furfural was oxidized to give fumaric acid. Fumaric acid was hydrogenated under high pressure with a palladium-rhenium/carbon catalyst to give 1,4-butanediol, and with a palladium/carbon catalyst to give succinic acid. Dimethyl succinate was synthesized from fumaric acid by esterification and hydrogenation under normal pressure. Fully biomass-based PBS was obtained by polycondensation of biomass-based 1,4-butanediol and biomass-based succinic acid or dimethyl succinate. The biomass carbon ratio calculated from C-14 concentrations measured by accelerator Mass spectroscopy (ANIS) verified that the PBS obtained in this study contained only biomass carbon, The polycondensation of biomass-based 1,4-butanediol and petroleum-based terephthalic acid or dimethyl terephthalate gave partially biomass-based poly(butylene tea:phthalate). which is an engineering plastic.

引用

页码：2760 / 2765

页数：6

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