Mobile high resolution xenon nuclear magnetic resonance spectroscopy in the earth's magnetic field -: art. no. 197602

被引:46
作者
Appelt, S
Häsing, FW
Kühn, H
Perlo, J
Blümich, B
机构
[1] Forschungszentrum Julich, Zent Inst Elekt, D-52425 Julich, Germany
[2] Rhein Westfal TH Aachen, Inst Tech Chem & Makromol Chem, D-52056 Aachen, Germany
关键词
D O I
10.1103/PhysRevLett.94.197602
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Conventional high resolution nuclear magnetic resonance (NMR) spectra are usually measured in homogeneous, high magnetic fields (> 1 T), which are produced by expensive and immobile superconducting magnets. We show that chemically resolved xenon (Xe) NMR spectroscopy of liquid samples can be measured in the Earth's magnetic field (similar to 5x10(-5) T) with a continuous flow of hyperpolarized Xe gas. It was found that the measured normalized Xe frequency shifts are significantly modified by the Xe polarization density, which causes different dipolar magnetic fields in the liquid and in the gas phases.
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页数:4
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共 26 条
[1]  
Abragam A., 2002, PRINCIPLES NUCL MAGN
[2]   Theory of spin-exchange optical pumping of 3He and 129Xe [J].
Appelt, S ;
Baranga, AB ;
Erickson, CJ ;
Romalis, MV ;
Young, AR ;
Happer, W .
PHYSICAL REVIEW A, 1998, 58 (02) :1412-1439
[3]   Proton magnetization enhancement of solvents with hyperpolarized xenon in very low-magnetic fields [J].
Appelt, S ;
Haesing, FW ;
Baer-Lang, S ;
Shah, NJ ;
Blümich, B .
CHEMICAL PHYSICS LETTERS, 2001, 348 (3-4) :263-269
[4]   Low field magnetic resonance images of polarized noble gases obtained with a dc superconducting quantum interference device [J].
Augustine, MP ;
Wong-Foy, A ;
Yarger, JL ;
Tomaselli, M ;
Pines, A ;
TonThat, DM ;
Clarke, J .
APPLIED PHYSICS LETTERS, 1998, 72 (15) :1908-1910
[5]   NUCLEAR MAGNETISM OF LIQUID-SYSTEMS IN THE EARTH FIELD RANGE [J].
BENE, GJ .
PHYSICS REPORTS-REVIEW SECTION OF PHYSICS LETTERS, 1980, 58 (04) :213-267
[6]   NUCLEAR POLARIZATION IN HE-3 GAS INDUCED BY OPTICAL PUMPING AND DIPOLAR EXCHANGE [J].
BOUCHIAT, MA ;
CARVER, TR ;
VARNUM, CM .
PHYSICAL REVIEW LETTERS, 1960, 5 (08) :373-375
[7]   An earth's field nuclear magnetic resonance apparatus suitable for pulsed gradient spin echo measurements of self-diffusion under Antarctic conditions [J].
Callaghan, PT ;
Eccles, CD ;
Seymour, JD .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1997, 68 (11) :4263-4270
[8]   A nuclear magnetic resonance study of Antarctic sea ice brine diffusivity [J].
Callaghan, PT ;
Dykstra, R ;
Eccles, CD ;
Haskell, TG ;
Seymour, JD .
COLD REGIONS SCIENCE AND TECHNOLOGY, 1999, 29 (02) :153-171
[9]   Two-dimensional imaging with a single-sided NMR probe [J].
Casanova, F ;
Blümich, B .
JOURNAL OF MAGNETIC RESONANCE, 2003, 163 (01) :38-45
[10]   POLARIZATION OF HE3 GAS BY OPTICAL PUMPING [J].
COLEGROVE, FD ;
SCHEARER, LD ;
WALTERS, GK .
PHYSICAL REVIEW, 1963, 132 (06) :2561-&