Polymeric (ethylenediamine)silver(I) 2,4,6-trinitrophenolate

被引:8
作者
Zhu, HL [1 ]
Wang, XJ [1 ]
Meng, FJ [1 ]
Liu, XY [1 ]
机构
[1] Wuhan Univ Sci & Engn, Dept Chem, Wuhan 430073, Peoples R China
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷
关键词
D O I
10.1107/S1600536803016635
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, catena-poly[[silver(I)-mu-ethylenediamine] 2,4,6-trinitrophenolate], {[Ag(C2H8)](C6H2N3O7)}(n), the Ag atom is bicoordinated, in a linear configuration, by two different N atoms from two symmetry-related ethylenediamine ligands, resulting in a linear polymeric helical chain with an [- Ag - N - C - C - N -](n) backbone. In the crystal structure, the components are connected by weak interactions between Ag and O atoms from the phenolate anion and the nitro groups. There are also weak hydrogen-bonding interactions between the NH2 groups and some of the O atoms of the anions, forming a three-dimensional network.
引用
收藏
页码:M698 / M699
页数:2
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