Crystal growth, thermal and linear optical properties of the non-centrosymmetric hydrated tetraborates Na2[B4O5(OH)4] • 3H2O (tincalconite) and K2[B4O5(OH)4] • 2H2O

被引：0
作者：
Hellwig, H [1 ]
Becker, P [1 ]
Ahrweiler, S [1 ]
Bohaty, L [1 ]
机构：
[1] Univ Cologne, Inst Kristallog, D-50674 Cologne, Germany
来源：
CRYSTAL RESEARCH AND TECHNOLOGY | 2000年 / 35卷 / 10期
关键词：
hydrated tetraborates; tincalconite; Na-2[B4O5(OH)(4)] center dot 3H(2)O; K-2[B4O5(OH)(4)] center dot 2H(2)O; optical properties; thermal properties;
D O I：
10.1002/1521-4079(200010)35:10<1151::AID-CRAT1151>3.0.CO;2-Q
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Large single crystals of the non-centrosymmetric hydrated tetraborates Na-2[B4O5(OH)(4)].3H(2)O ("tincalconite") (point group 32) and K-2[B4O5(OH)(4)].2H(2)O (point group 222) were grown from aqueous solutions and the linear optical properties (refractive indices between 365 nm and 1530 nm and unpolarized absorption spectra) as a basis for nonlinear optical investigations were determined The uniaxial positive sodium salt is not phase matchable; in the orthorhombic potassium compound type I phase matching is possible in the near infrared region. Thermal investigations indicate a phase transition at similar to 285 K for Na-2[B4O5(OH)(4)].3H(2)O.
引用
收藏
页码：1151 / 1161
页数：11
相关论文
共 50 条
  • [41] First principles study of electronic structure, structural and optical properties of Mg3Si2O5(OH)4
    Adebayo, G. A.
    Zhanabergenov, Zh.
    Emazarov, U.
    Badmus, B. S.
    Anusionwu, B. C.
    APPLIED CLAY SCIENCE, 2014, 93-94 : 8 - 11
  • [42] Effect of K2WO4 on structure and properties of low melting glasses in K2O-Fe2O3-P2O5 system as sealing materials
    Ebrahium, Mohamad M.
    Abo-Mosallam, H. A.
    Mahdy, Ebrahim A.
    CERAMICS INTERNATIONAL, 2024, 50 (01) : 941 - 949
  • [43] Effect of Bi2O3 content on physical and optical properties of 15Li2O-15K2O-xBi2O3-(65-x) B2O3: 5V2O5 glass system
    Subhadra, M.
    Kistaiah, P.
    PHYSICA B-CONDENSED MATTER, 2011, 406 (08) : 1501 - 1505
  • [44] Effect of B2O3 Addition on Thermal, Structure, and Sealing Properties V2O5-P2O5-ZnO Glass
    Sung, Aram
    Kim, Yurian
    Kim, Hyungsun
    KOREAN JOURNAL OF MATERIALS RESEARCH, 2016, 26 (10): : 549 - 555
  • [45] Photoelectrochemical properties of Fe2O3 nanorods grown with an Na2 SO4 additive
    Choi, Hayoung
    Ryu, Hyukhyun
    Lee, Won-Jae
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2018, 63 : 41 - 47
  • [46] Growth of Cs2Ni(SO4)2•6H2O and Rb2Ni(SO4)2•6H2O and their Characteristics
    Manomenova, Vera L.
    Rudneva, E. B.
    Voloshin, A. E.
    Malahova, L. F.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2005, 61 : C438 - C439
  • [47] Optical and thermal properties of P2O5-Na2O-CaO-Al2O3:CoO glasses doped with transition metals
    Colak, S. Cetinkaya
    Aral, E.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 (15) : 4935 - 4939
  • [48] Syntheses, Crystal Structures, and Optical Properties of Indium Arsenic(III) Oxide Halides: In2(As2O5)Cl2 and In4(As2O5)(As3O7)Br3
    Jiang, Xiao-Ming
    Xu, Zhong-Ning
    Zhao, Zhong-Yan
    Guo, Sheng-Ping
    Guo, Guo-Cong
    Huang, Jin-Shun
    EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2011, (26) : 4069 - 4076
  • [49] Growth and optical properties of nonlinear optical crystal Rb4Li2TiOGe4O12
    Tang, Chuan
    Xia, Mingjun
    Li, Rukang
    JOURNAL OF CRYSTAL GROWTH, 2021, 555
  • [50] Optical properties of Na2W4O13 crystals
    Itoh, M
    Oishi, S
    MATERIALS RESEARCH BULLETIN, 2001, 36 (7-8) : 1495 - 1504
12345