Crystal growth, thermal and linear optical properties of the non-centrosymmetric hydrated tetraborates Na2[B4O5(OH)4] • 3H2O (tincalconite) and K2[B4O5(OH)4] • 2H2O

被引：0

作者：

Hellwig, H ^{[1
]}

Becker, P ^{[1
]}

Ahrweiler, S ^{[1
]}

Bohaty, L ^{[1
]}

机构：

[1] Univ Cologne, Inst Kristallog, D-50674 Cologne, Germany

来源：

CRYSTAL RESEARCH AND TECHNOLOGY | 2000年 / 35卷 / 10期

关键词：

hydrated tetraborates; tincalconite; Na-2[B4O5(OH)(4)] center dot 3H(2)O; K-2[B4O5(OH)(4)] center dot 2H(2)O; optical properties; thermal properties;

D O I：

10.1002/1521-4079(200010)35:10<1151::AID-CRAT1151>3.0.CO;2-Q

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

Large single crystals of the non-centrosymmetric hydrated tetraborates Na-2[B4O5(OH)(4)].3H(2)O ("tincalconite") (point group 32) and K-2[B4O5(OH)(4)].2H(2)O (point group 222) were grown from aqueous solutions and the linear optical properties (refractive indices between 365 nm and 1530 nm and unpolarized absorption spectra) as a basis for nonlinear optical investigations were determined The uniaxial positive sodium salt is not phase matchable; in the orthorhombic potassium compound type I phase matching is possible in the near infrared region. Thermal investigations indicate a phase transition at similar to 285 K for Na-2[B4O5(OH)(4)].3H(2)O.

引用

页码：1151 / 1161

页数：11

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