Carbon-sulfur bond formation between a ruthenium-coordinated thiyl radical and methyl ketones

被引：20

作者：

Poturovic, S ^{[1
]}

Mashuta, MS ^{[1
]}

Grapperhaus, CA ^{[1
]}

机构：

[1] Univ Louisville, Dept Chem, Louisville, KY 40292 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 12期

关键词：

ketones; radicals; ruthenium; sulfur;

D O I：

10.1002/anie.200462713

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A metal-coordinated thiyl radical was revealed by the electrochemical oxidation of a ruthenium(III)-thiolate in acetone (and related ketones). The subsequent reaction between the radical intermediate and acetone resulted in C-S bond formation and ultimately a ruthenium(III)-thioether product (see picture). A mechanism that involves reaction of the enol tautomer of acetone with the radical is proposed. (Figure Presented) © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1883 / 1887

页数：5

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