Zn(tmp)2:: A versatile base for the selective functionalization of C-H bonds

被引：56

作者：

Hlavinka, Mark L. ^{[1
]}

Hagadorn, John R. ^{[1
]}

机构：

[1] Univ Colorado, Dept Chem & Biochem, Boulder, CO 80309 USA

来源：

ORGANOMETALLICS | 2007年 / 26卷 / 17期

关键词：

D O I：

10.1021/om700475t

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Zn(tMP)(2) (tMP = 2,2,6,6-tetramethylpiperidinyl anion) is an effective base for the mild deprotonation of a broad range of substrates. Functionalized organozincs thus prepared are conveniently coupled with aryl bromides using typical Pd-catalyzed coupling methods.

引用

页码：4105 / 4108

页数：4

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