Transition metal-catalyzed [2,3]-sigmatropic rearrangements of ylides: An update of the most recent advances

被引：115

作者：

Sheng, Zhe ^{[1
,2
]}

Zhang, Zhikun ^{[1
]}

Chu, Changhu ^{[2
]}

Zhang, Yan ^{[1
]}

Wang, Jianbo ^{[1
]}

机构：

[1] Peking Univ, BNLMS, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem, Beijing 100871, Peoples R China

[2] East China Univ Sci & Technol, Sch Pharm, Shanghai Key Lab New Drug Design, 130 Meilong Rd, Shanghai 200237, Peoples R China

来源：

TETRAHEDRON | 2017年 / 73卷 / 29期

关键词：

Transition-metal-catalysis; Metal carbene; Ylide; Diazo compounds; 2,3]-sigmatropic rearrangement; OXO GOLD CARBENES; C BOND FORMATION; RHODIUM(II)-CATALYZED STEREOCONTROLLED SYNTHESIS; 2,3 SIGMATROPIC REARRANGEMENT; OXONIUM YLIDE; STEREOSELECTIVE-SYNTHESIS; DONOR/ACCEPTOR CARBENOIDS; TANDEM YLIDE; N-TOSYLHYDRAZONES; DIAZO-COMPOUNDS;

D O I：

10.1016/j.tet.2016.11.045

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[2,3]-sigmatropic rearrangements of ylides are useful methods for synthesizing functional molecules, especially for these containing heteroatoms. This short report focuses on the most recent advances in transition-metal-catalyzed [2,3]-sigmatropic rearrangements of sulfonium, oxonium, and ammonium ylides. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：4011 / 4022

页数：12

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