Diaquabis(2,4-dibromo-6-formyl-phenolato-κ 2N,N′)zinc(II)

被引:6
作者
Chen, Xian-Ming
Zhang, Shu-Hua [1 ]
Jin, Li-Xia
Liu, Zheng
Yan, Yang
机构
[1] Guilin Univ Technol, Dept Chem & Mat Engn, Key Lab Nonferrous Met Mat & Proc Technol, Minist Educ, Guilin 541004, Peoples R China
[2] Yulin Teachers Coll, Yulin 537000, Guangxi, Peoples R China
关键词
single-crystal X-ray study; T=293 K; mean sigma(C-C)=0.009 angstrom; R factor=0.041; wR factor=0.127; data-to-parameter ratio=18.5;
D O I
10.1107/S1600536807018259
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Zn(C7H3Br2O2)(2)(H2O)(2)], the Zn-II atom is six-coordinated in a slightly distorted octahedral coordination geometry by four O atoms of two 3,5-dibromo-2-hydroxybenzaldehyde ligands and by two water molecules. The Zn-O bond lengths lie in the range 2.040 (4)-2.121 (4) angstrom, and the angles subtended at the Zn-II atom range from 84.10 (18) to 96.64 ( 17)degrees. The molecules are linked into a chain along the a axis by O-H . . . O and O-H . . . Br hydrogen bonds.
引用
收藏
页码:M1321 / U57
页数:10
相关论文
共 9 条
[1]  
*BRUK AXS INC, 2001, SAINT VERS 6 45 SAMR
[2]   TOPOCHEMISTRY .2. PHOTOCHEMISTRY OF TRANS-CINNAMIC ACIDS [J].
COHEN, MD ;
SCHMIDT, GMJ ;
SONNTAG, FI .
JOURNAL OF THE CHEMICAL SOCIETY, 1964, (JUN) :2000-&
[3]  
Desiraju G. R., 1989, DESIGN ORGANIC SOLID
[4]  
Johnson C. K., 1976, ORNL5138
[5]   TOPOCHEMISTRY .3. CRYSTAL CHEMISTRY OF SOME TRANS-CINNAMIC ACIDS [J].
SCHMIDT, GMJ .
JOURNAL OF THE CHEMICAL SOCIETY, 1964, (JUN) :2014-&
[6]  
Sheldrick G. M., 1997, SHELXS 97 PROGRAM CR, P38
[7]  
Sheldrick G.M., 1996, SADABS VERSION 2008
[8]  
XIAO Y, 2002, J GUANGZI NORMAL U, V20, P81
[9]   Supramolecular chemistry of halogens:: Complementary features of inorganic (M-X) and organic (C-X′) halogens applied to M-X•••X′-C halogen bond formation [J].
Zordan, F ;
Brammer, L ;
Sherwood, P .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (16) :5979-5989