Universal 4-qualifiable fluorene-based building blocks for potential optoelectronic applications

In the design of conjugated molecules, modular production enables materials to easily realize structure modification and precisely tune their photoelectrical property. Construction of a novel and universal building block is crucial to design and manufacture high performance and stable conjugated molecules for optoelectronic application. Herein, we originally demonstrated a universal 4-qualifiable fluorene-based building block, which is a fundamental molecular segment to functionalize and obtain novel conjugated materials. Compared to the traditional modification at 9-site, additional 4-position functionalization provided an exciting blueprint to not only tune electronic structure and excited state via p-n molecular design engineering and space charge-transfer strategy, but also allow for optimizing intermolecular arrangement and obtaining solution-processing ability. The introduction of the 4-site substituent in fluorene based semiconductors may endow materials with unique properties. Finally, we successfully prepared two stable deep-blue light-emitting conjugated polymer, PODOPF and PODOF, by utilizing the 4-substituent fluorene based building block. It is believable that the performance, stability and processibility of reported outstanding fluorene-based conjugated molecules can be further optimized based on this universal building block. (c) 2022 Published by Elsevier B.V. on behalf of Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences.