Uranyl α-dioximates with neutral ligands

被引：4

作者：

Beirakhov, A. G. ^{[1
]}

Orlova, I. M. ^{[1
]}

Il'in, E. G. ^{[1
]}

Gorbunova, Yu. E. ^{[1
]}

Mikhailov, Yu. N. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 52卷 / 12期

关键词：

D O I：

10.1134/S0036023607120169

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The interaction of uranyl compounds with different alpha-dioximes has been studied. Uranyl complexes with glyoxime, methylglyoxime, dimethylglyoxime, and 1,2-cyclohexanedionedioxime have been synthesized. The X-ray diffraction study of single crystals of [UO2(C3H5N2O2)(2){(NH2)(2)CO}(2)], [UO2(C6H9N2O2)(2)(H2O)(2)]center dot H2O, [UO2(C6H9N2O2)(2)(H2O)(2)]center dot 6H(2)O, and [UO2(C6H9N2O2)(2)(H2O)(2)](2)(CH3CONH2)(2)center dot 6H(2)O showed a bidentate cyclic coordination of alpha-dioximes to the central atom through only one oxime group.

引用

页码：1896 / 1907

页数：12