Preparation and crystal structure of [P(C6H5)(4)](2)[2-SnCl(C6H5)(2)B10H9]

被引：6

作者：

Nachtigal, C ^{[1
]}

Preetz, W ^{[1
]}

机构：

[1] CHRISTIAN ALBRECHTS UNIV KIEL,INST ANORGAN CHEM,D-24098 KIEL,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1996年 / 51卷 / 08期

关键词：

2-(chlorodiphenyltin)-nonahydro-closo-decaborate(2-); crystal structure;

D O I：

10.1515/znb-1996-0801

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By reaction of [N(C4H9)(4)](2)[B10H10] with chlorotriphenyltin in acetonitrile at 70 degrees C the 2-(chlorodiphenyltin)-decaborate anion [2-SnCl(C6H5)(2)B10H9](2-) is formed and can be separated from the starting compound by ion exchange chromatography on diethylaminoethyl (DEAE) cellulose. The X-ray structure of [P(C6H5)(4)](2)[2-SnCl(C6H5)(2)B10H9]] (monoclinic space group P 2(1)/c with a=17.263(2), b=13.045(3), c=26.171(2)Angstrom beta=102.882(7)degrees) reveals that the SnCl(C6H5)(2) substituent is bonded with a B2-Sn distance of 2.168(4) Angstrom.

引用

页码：1061 / 1063

页数：3

共 50 条

[1] Synthesis and crystal structure of [P(C6H5)(4)](2)[2-SnCl2(C6H5)B10H9]
Nachtigal, C
Preetz, W
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1997, 52 (08): : 975 - 977
[2] PREPARATION, B-11 NMR AND VIBRATIONAL-SPECTRA OF MULTIALKYLATED HEXABORATES AND CRYSTAL-STRUCTURES OF CIS-[P(C6H5)(4)][B6H5(CH3)(2)] AND TRANS-[P(C6H5)(4)][B6H5(CH3)(2)] AND MER-[P(C6H5)(4)][B6H4(CH3)(3)]
BAURMEISTER, J
FRANKEN, A
PREETZ, W
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1995, 50 (05): : 772 - 780
[3] Crystal structure of tetraphenylphosphonium monothiocyanatohydro-closo-decaborate, [P(C6H5)(4)](2)[2-(SCN)B10H9]center dot CH3CN
Nachtigal, C
Preetz, W
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1996, 622 (03): : 509 - 512
[4] Synthesis and crystal structures of (p-bromobenzyl)triphenylphosphonium bromides, [(p-Br-C6H4-CH2)P(C6H5)(3)](+) Br-; [(p-Br-C6H4-CH2)P(C6H5)(3)](+) Br-2(-) and [(p-Br-C6H4-CH2)P(C6H5)(3)](+) Br-3(-)
Vogt, H
WulffMolder, D
Meisel, M
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (10): : 1443 - 1448
[5] Preparation, B-11, C-13, H-1 NMR and vibrational spectra of phenylundecahydro-closo-dodecaborate(2-) and crystal structure of [As(C6H5)(4)](2)[(C6H5)B12H11]
Koch, T
Preetz, W
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1997, 52 (08): : 935 - 938
[6] Synthesis and crystal structure of [P(C6H5)(4)][2,9-{N,N'-(2-NH-(C5H4N))}B10H8]
Nachtigal, C
Preetz, W
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (09): : 1489 - 1491
[7] PREPARATION AND CRYSTAL-STRUCTURE OF [P(C6H5)(4)]CL-3
JANSEN, M
STROJEK, S
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1995, 50 (08): : 1171 - 1174
[8] Preparation, B-11 NMR, vibrational sprectra and crystal structure of bis(tetraphenylphosphonium) 2-[2-(2-pyridyl-amino)-pyrid-5-yl]-closo-decaborate, [P(C6H5)4](2) [2-(2-(2-(C5H4N)-NH)-(C5H3N)-5)B10H9]
Nachtigal, C
Preetz, W
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (11): : 1559 - 1562
[9] Preparation, B-11,C-13, H-1 NMR and vibrational spectra of mu-dimethylene-bis-hexahydro-closo-hexaborate, [B6H6(CH2)(2)B6H6](2-), and the crystal structures of [As(C6H5)(4)](2)[B6H6(CH2)(2)][B6H6]center dot[(CH3)(2)CO] and [P(C6H5)(4)](2)[B6H6(CH)(2)B6H6]center dot[C2H5OH]
Lubbe, W
Preetz, W
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1996, 51 (03): : 363 - 369
[10] THE DIRECT ELECTROCHEMICAL SYNTHESIS OF THE NOVEL COPPER(I) COMPLEX CU2[OC6CL4(OH)]2[(C6H5)2PCH2P(C6H5)2]2
ANNAN, TA
KICKHAM, JE
TUCK, DG
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1991, 69 (02): : 251 - 256

← 1 2 3 4 5 →