C ion-implanted TiO2 thin film for photocatalytic applications

被引:42
作者
Impellizzeri, G. [1 ]
Scuderi, V. [1 ]
Romano, L. [1 ,2 ]
Napolitani, E. [1 ,3 ]
Sanz, R. [1 ]
Carles, R. [4 ]
Privitera, V. [1 ]
机构
[1] CNR IMM MATIS, I-95123 Catania, Italy
[2] Univ Catania, Dipartimento Fis & Astron, I-95123 Catania, Italy
[3] Univ Padua, Dipartimento Fis & Astron, I-35131 Padua, Italy
[4] Univ Toulouse, CEMES CNRS, F-31055 Toulouse 4, France
关键词
WATER; ANATASE; NANOMATERIALS; TECHNOLOGY;
D O I
10.1063/1.4915111
中图分类号
O59 [应用物理学];
学科分类号
摘要
Third-generation TiO2 photocatalysts were prepared by implantation of C+ ions into 110 nm thick TiO2 films. An accurate structural investigation was performed by Rutherford backscattering spectrometry, secondary ion mass spectrometry, X-ray diffraction, Raman-luminescence spectroscopy, and UV/VIS optical characterization. The C doping locally modified the TiO2 pure films, lowering the band-gap energy from 3.3 eV to a value of 1.8 eV, making the material sensitive to visible light. The synthesized materials are photocatalytically active in the degradation of organic compounds in water under both UV and visible light irradiation, without the help of any additional thermal treatment. These results increase the understanding of the C-doped titanium dioxide, helpful for future environmental applications. (C) 2015 AIP Publishing LLC.
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页数:6
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