Thermal behaviour of Co(II), Ni(II), Cu(II), Zn(II), Hg(II) and Pd(II) complexes with isatin-β-thiosemicarbazone

被引：37

作者：

Konstantinovic, Sandra S.

Radovanovic, Blaga C.

Krkljes, Aleksandra

机构：

[1] Fac Technol, Leskovac 16000, Serbia

[2] Fac Sci, Dept Chem, Nish 18000, Serbia

[3] INN Vinca, Belgrade 11000, Serbia

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2007年 / 90卷 / 02期

关键词：

Co(II); Ni(II); Cu(II); Zn(H); Hg(H); Pd(II) complexes; isatin-beta-thiosemicarbazone; thermal stability;

D O I：

10.1007/s10973-006-7794-9

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The isatin-beta-thiosemicarbazone (ITC) complexes of Co(II), Ni(II), Cu(II), Zn(II), Hg(II) and Pd(II) were prepared and characterized by elemental analysis, as well as molar conductivity, magnetic susceptibility, FTIR, UV-Vis and H-1 NMR spectroscopic methods. The complexes were also studied for its thermal stability. They all behaviour as anhydrous complexes and its thermolysis passes through the stages of deamination (517-547 K) and complete thermal decomposition (619-735 K).

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页码：525 / 531

页数：7

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