A nickel(II) fumarate complex with o-phenanthroline

被引：6

作者：

Ma, JF ^{[1
]}

Yang, J ^{[1
]}

Liu, JF ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Changchun 130024, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷

关键词：

D O I：

10.1107/S1600536803019408

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the dinuclear and centrosymmetric title complex, fumarato-bis[aquabis(1,10-phenanthroline)nickel(II)] fumarate hexadecahydrate, [Ni-2(C4H2O4)(C12H8N2)(4)(H2O)(2)]-(C4H2O4).16H(2)O or [Ni-2(phen)(4)L(H2O)(2)]L.16H(2)O, where phen = 1,10-phenanthroline and L2- = fumarate, the nickel(II) canon is six-coordinated by two O atoms, one from a water molecule and the other from one end of a bridging L2- anion, and four N atoms from two bidentate phen ligands. Each of the two independent L2- anions is located about an inversion centre. Interestingly, one L2- anion is bridging and the other acts as a counter-ion. The [Ni-2(phen)(4)L(H2O)(2)](2+) cations, water molecules and L2- anions are connected through complex hydrogen-bonding interactions to form a three-dimensional structure.

引用

页码：M900 / M902

页数：3

共 50 条

[41] REDOX EQUILIBRIUM IN THE ACCEPTOR QUINONE COMPLEX OF ISOLATED REACTION CENTERS AND THE MODE OF ACTION OF O-PHENANTHROLINE [J].

WRAIGHT, CA ;

STEIN, RR .

FEBS LETTERS, 1980, 113 (01) :73-77

[42] Crystal structure of copper(II) pivaloyltrifluoracetonate adducts with o-phenanthroline and 2,2'-dipyridyl [J].

Gorbenko, OY ;

Troyanov, SI ;

Meetsma, A ;

Bosak, AA .

POLYHEDRON, 1997, 16 (12) :1999-2004

[43] Heterogeneous Photodecolorization of Methyl Green Catalyzed by Fe(II)-o-Phenanthroline/Zeolite Y Nanocluster [J].

Nezamzadeh-Ejhieh, Alireza ;

Shahriari, Elahe .

INTERNATIONAL JOURNAL OF PHOTOENERGY, 2011, 2011

[44] INHIBITION OF GLUTAMIC DEHYDROGENASE BY O-PHENANTHROLINE AND ITS ANALOGS [J].

YIELDING, KL ;

TOMKINS, GM .

BIOCHIMICA ET BIOPHYSICA ACTA, 1962, 62 (02) :327-&

[45] Note on the use of the o-phenanthroline ferrous complex as an indicator in the ceric sulfate titration of blood sugar [J].

MacFadyen, DA ;

Van Slyke, DD .

JOURNAL OF BIOLOGICAL CHEMISTRY, 1943, 149 (02) :527-527

[46] Synthesis and characterization of electrochemiluminescent ruthenium(II) complexes containing o-phenanthroline and various α-diimine ligands [J].

Kim, BH ;

Lee, DN ;

Park, HJ ;

Min, JH ;

Jun, YM ;

Park, SJ ;

Lee, WY .

TALANTA, 2004, 62 (03) :595-602

[47] CATALASE ACTIVITY OF VARIOUS FORMS OF MANGANESE(II) COMPLEXES OF O-PHENANTHROLINE AND ALPHA,ALPHA'-DIPYRIDYL [J].

TIGINYANU, YD ;

SYCHEV, AY ;

BERDNIKO.VM .

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY, 1971, 45 (07) :975-+

[48] Thermodynamics of vaporization of the mixed-ligand complex of sodium dipivaloylmethanate with o-phenanthroline Na(thd)(phen) [J].

Malkerova, I. P. ;

Alikhanyan, A. S. ;

Tsymbarenko, D. M. ;

Kuzmina, N. P. .

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2016, 61 (10) :1292-1295

[49] An aquazinc(II) complex of 1,10-phenanthroline with fumarate counter-ions [J].

Yang, J ;

Ma, JF ;

Liu, JF .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 :M324-M326

[50] An aquacadmium(II) complex of 1,10-phenanthroline with a fumarate counter-ion [J].

Yang, J ;

Ma, JF ;

Li, L ;

Liu, JF .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 :M568-M570

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