Identification of sulfated steroidal glycosides from the starfish Heliaster helianthus by electrospray ionization mass spectrometry

被引：9

作者：

Maier, Marta S. ^{[1
]}

Centurion, Romina

Muniain, Claudia

Haddad, Renato

Eberlin, Marcos N.

机构：

[1] Univ Buenos Aires, Fac Ciencias Exactas & Nat, Dept Quim Organ, Pabellon 2,Ciudad Univ, RA-1428 Buenos Aires, DF, Argentina

[2] Univ Buenos Aires, Fac Ciencias Exactas & Nat, CONICET, FCEN,UMYMFOR, RA-1428 Buenos Aires, DF, Argentina

[3] Museo Argentino Ciencias Nat Bernardino Rivadavia, RA-1405 Buenos Aires, DF, Argentina

[4] Univ Estadual Campinas, BR-13083970 Campinas, SP, Brazil

来源：

ARKIVOC | 2007年

关键词：

starfish; Heliaster helianthus; sulfated glycosides; electrospray ionization tandem mass spectrometry;

D O I：

10.3998/ark.5550190.0008.726

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The starfish Heliaster helianthus contains Thornasteroside A (1) and Helianthoside (2) and its isomer (3) as the major sulfated steroidal glycosides. Saponin containing fractions obtained by purification of extracts of H. helianthus induced escape reactions and mortality in the limpets Siphonaria lessoni and Fissurella radiosa. ESI-MS and ESI-MS/MS were successfully applied to the rapid screening of two cytotoxic fractions obtained by purification of the ethanolic extracts of arms and central disks dissected from H. helianthus. Three major compounds were identified, together with minor sulfated steroidal mono- and diglycosides of polyhydroxysteroids.

引用

页码：301 / 309

页数：9

共 50 条

[1] Stereospecific fragmentation of starfish polyhydroxysteroids in electrospray ionization mass spectrometry
R. S. Popov
P. S. Dmitrenok
Journal of Analytical Chemistry, 2016, 71 : 1368 - 1376
[2] Stereospecific fragmentation of starfish polyhydroxysteroids in electrospray ionization mass spectrometry
Popov, R. S.
Dmitrenok, P. S.
JOURNAL OF ANALYTICAL CHEMISTRY, 2016, 71 (14) : 1368 - 1376
[3] New Steroidal Glycosides from the Starfish Acanthaster planci
L. T. Vien
T. T. H. Hanh
P. T. T. Huong
V. A. Tu
N. V. Thanh
E. G. Lyakhova
N. X. Cuong
N. H. Nam
P. V. Kiem
C. V. Minh
A. A. Kicha
V. A. Stonik
Chemistry of Natural Compounds, 2016, 52 : 1056 - 1060
[4] SULFATED STEROIDAL GLYCOSIDES, REGULUSOSIDES S1 AND S2, FROM THE TROPICAL STARFISH Pentaceraster regulus
Kicha, A. A.
Ivanchina, N. V.
Malyarenko, T. V.
Kalinovsky, A. I.
Dmitrenok, P. S.
CHEMISTRY OF NATURAL COMPOUNDS, 2017, 53 (01) : 88 - 92
[5] Sulfated Steroidal Glycosides, Regulusosides S1 and S2, from the Tropical Starfish Pentaceraster regulus
A. A. Kicha
N. V. Ivanchina
T. V. Malyarenko
A. I. Kalinovsky
P. S. Dmitrenok
Chemistry of Natural Compounds, 2017, 53 : 88 - 92
[6] Identification and fragmentation of hydrolyzed aluminum species by electrospray ionization tandem mass spectrometry
Sarpola, A
Hietapelto, V
Jalonen, J
Jokela, J
Laitinen, RS
Rämö, J
JOURNAL OF MASS SPECTROMETRY, 2004, 39 (10): : 1209 - 1218
[7] Sulfated steroid glycosides from the Viet Namese starfish Linckia laevigata
A. A. Kicha
N. V. Ivanchina
A. I. Kalinovskii
P. S. Dmitrenok
E. V. Sokolova
I. G. Agafonova
Chemistry of Natural Compounds, 2007, 43 : 76 - 80
[8] Sulfated steroid glycosides from the Viet Namese starfish Linckia laevigata
Kicha, A. A.
Ivanchina, N. V.
Kalinovskii, A. I.
Dmitrenok, P. S.
Sokolova, E. V.
Agafonova, I. G.
CHEMISTRY OF NATURAL COMPOUNDS, 2007, 43 (01) : 76 - 80
[9] Two new polyhydroxylated steroidal glycosides from the starfish Culcita novaeguineae
Lu, Yun-Yang
Wang, Min-Chang
Liu, Ke
Zhang, Wei
Liu, Yang
Tang, Hai-Feng
NATURAL PRODUCT RESEARCH, 2022, 36 (08) : 2118 - 2124
[10] Structural elucidation and identification of alkaloids in Rhizoma Coptidis by electrospray ionization tandem mass spectrometry
Wang, DW
Liu, ZQ
Guo, MQ
Liu, SY
JOURNAL OF MASS SPECTROMETRY, 2004, 39 (11): : 1356 - 1365

← 1 2 3 4 5 →