Highly Permeable Macroporous Polymers Synthesized from Pickering Medium and High Internal Phase Emulsion Templates

被引:287
作者
Ikem, Vivian O. [1 ]
Menner, Angelika [1 ]
Horozov, Tommy S. [2 ]
Bismarck, Alexander [1 ]
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem Engn, Polymer &Composite Engn PaCE Grp, London SW7 2AZ, England
[2] Univ Hull, Dept Chem, Surfactant & Colloid Grp, Kingston Upon Hull HU6 7RX, N Humberside, England
基金
英国工程与自然科学研究理事会;
关键词
PARTICLE-STABILIZED EMULSIONS; POROUS POLYMERS; SILICA PARTICLES; RATIO EMULSIONS; FOAMS; MORPHOLOGY; POLYMERIZATION; POROSITY;
D O I
10.1002/adma.201000729
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Open porous poly-Pickering-M/HIPEs with permeabilities of up to 2.6 D were prepared by polymerisation of Pickering-M/HIPEs to which small amounts of surfactant were added. The permeability of these poly-Pickering-M/HIPEs is more than 5 times that of conventional polyHIPEs. This approach allows the synthesis of a novel class of permeable particle reinforced macroporous polymers with significant potential for practical exploitation.
引用
收藏
页码:3588 / +
页数:6
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