Dipicolylglycyl-phenylalanine zinc(II): a metallopeptide with a built-in conformational switch and its homochiral helical coordination polymer

被引:28
作者
Niklas, N
Hampel, F
Alsfasser, R
机构
[1] Univ Erlangen Nurnberg, Inst Inorgan Chem, D-91058 Erlangen, Germany
[2] Univ Erlangen Nurnberg, Inst Organ Chem, D-91054 Erlangen, Germany
关键词
D O I
10.1039/b303172a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The peptide-zinc complex [(Dpg-Phe)Zn](2+) (Dpg = N,N-dipicolylglycine; Phe = phenylalanine) reversibly forms a homochiral P-helical coordination polymer upon switching the pH from mildly basic to mildly acidic.
引用
收藏
页码:1586 / 1587
页数:2
相关论文
共 22 条
[1]   Amide group coordination to the Pb2+ ion [J].
Battistuzzi, G ;
Borsari, M ;
Menabue, L ;
Saladini, M ;
Sola, M .
INORGANIC CHEMISTRY, 1996, 35 (14) :4239-4247
[2]   Enantiomerically pure chiral coordination polymers:: Synthesis, spectroscopy, and electrochemistry in solution and on surfaces [J].
Bernhard, S ;
Takada, K ;
Díaz, DJ ;
Abruña, HD ;
Mürner, H .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (42) :10265-10271
[3]   From helicate to infinite coordination polymer: crystal and molecular structures of silver(I) complexes of readily prepared di-Schiff bases [J].
Bowyer, PK ;
Porter, KA ;
Rae, AD ;
Willis, AC ;
Wild, SB .
CHEMICAL COMMUNICATIONS, 1998, (10) :1153-1154
[4]   Stereoselective synthesis of chiral coordination polymers with partial control of the rigid main chain topology [J].
Chen, JB ;
MacDonnell, FM .
CHEMICAL COMMUNICATIONS, 1999, (24) :2529-2530
[5]  
Coe BJ, 1999, CHEM-EUR J, V5, P2464, DOI 10.1002/(SICI)1521-3765(19990903)5:9<2464::AID-CHEM2464>3.0.CO
[6]  
2-L
[7]   Preparation, characterization, and X-ray crystal structures of helical and syndiotactic zinc-based coordination polymers [J].
Ellis, WW ;
Schmitz, M ;
Arif, AA ;
Stang, PJ .
INORGANIC CHEMISTRY, 2000, 39 (12) :2547-2557
[8]   Synthesis and structure of a helical coordination polymer:: {[Zn2(bdaip)(μ-OH)(OH)]NO3•2H2O}∞ (Hbdaip=2,6-bis{N-[2-(dimethylamino)ethyl]-iminomethyl}-4-methylpihenol) [J].
Erxleben, A .
INORGANIC CHEMISTRY, 2001, 40 (02) :412-+
[9]  
EVANS DA, 1992, ANGEW CHEM INT EDIT, V31, P31
[10]   Crystal engineering of NLO materials based on metal-organic coordination networks [J].
Evans, OR ;
Lin, WB .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :511-522