Recent Advances in Copper-mediated Direct Biaryl Coupling

被引:135
作者
Hirano, Koji [1 ]
Miura, Masahiro [1 ]
机构
[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
关键词
C-H BONDS; TRANSITION-METAL CATALYSIS; PYRIDINE N-OXIDES; DIRECT ARYLATION; CARBON-HYDROGEN; SIMPLE ARENES; UNACTIVATED ARENES; ARYLBORONIC ESTERS; MILD CONDITIONS; AZOLE COMPOUNDS;
D O I
10.1246/cl.150354
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Copper salts and complexes have recently received significant attention as less expensive, abundant, and unique alternatives to noble transition-metal catalysts such as palladium, rhodium, and ruthenium, in the research field of C H activation. This highlight review focuses on recent advances in copper-mediated biaryl coupling via aromatic C H cleavage, and the scope and limitations are briefly summarized.
引用
收藏
页码:868 / 873
页数:6
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