Ionic liquids, 3. Synthesis and utilisation of protic imidazolium salts in homogeneous catalysis

被引：60
|
作者：
Picquet, M
Tkatchenko, I
Tommasi, I
Wasserscheid, P
Zimmermann, J
机构：
[1] CNRS, Lab Synth & Electrosynth Organomet, FRE 2595, Fac Sci Mirande, F-21078 Dijon, France
[2] Univ Bari, Dept Chem, I-70126 Bari, Italy
[3] Rhein Westfal TH Aachen, Inst Tech & Makromol Chem, D-52074 Aachen, Germany
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2003年 / 345卷 / 08期
关键词：
ionic liquids; protonation; imidazoles; dimerisation; ring closing metathesis;
D O I：
10.1002/adsc.200303025
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Protonation of 1-alkylimidazoles provides halogen-free salts which act as ionic liquids and proton reservoir in proton- and metal-assisted catalytic processes like dimerisation of methyl acrylate and ring closing metathesis, and lead to significant improvements both in activity and selectivity.
引用
收藏
页码：959 / 962
页数：4
相关论文
共 50 条
  • [1] Synthesis of novel spiro imidazolium salts as chiral ionic liquids
    Patil, Mahesh L.
    Rao, C. V. Laxman
    Takizawa, Shinobu
    Takenaka, Kazuhiro
    Onitsuka, Kiyotaka
    Sasai, Hiroaki
    TETRAHEDRON, 2007, 63 (51) : 12702 - 12711
  • [2] Homogeneous catalysis in ionic liquids
    Giernoth, Ralf
    IN SITU NMR METHODS IN CATALYSIS, 2007, 276 : 1 - 23
  • [3] Homogeneous catalysis in ionic liquids
    Doherty, Simon (simon.doherty@ncl.ac.uk), 1600, Royal Society of Chemistry (2014-January):
  • [4] Ultrasound assisted synthesis of imidazolium salts: An efficient way to ionic liquids
    Zbancioc, Gheorghita
    Mangalagiu, Ione I.
    Moldoveanu, Costel
    ULTRASONICS SONOCHEMISTRY, 2015, 23 : 376 - 384
  • [5] Inter- and Intramolecular Interactions in Imidazolium Protic Ionic Liquids
    Moschovi, Anastasia Maria
    Dracopoulos, Vassileios
    Nikolakis, Vladimiros
    JOURNAL OF PHYSICAL CHEMISTRY B, 2014, 118 (29): : 8673 - 8683
  • [6] Membrane interactions of ionic liquids and imidazolium salts
    Wang D.
    Galla H.-J.
    Drücker P.
    Biophysical Reviews, 2018, 10 (3) : 735 - 746
  • [7] Hydrogen bond in imidazolium based protic and aprotic ionic liquids
    Watanabe, Hikari
    Doi, Hiroyuki
    Saito, Soshi
    Matsugami, Masaru
    Fujii, Kenta
    Kanzaki, Ryo
    Kameda, Yasuo
    Umebayashi, Yasuhiro
    JOURNAL OF MOLECULAR LIQUIDS, 2016, 217 : 35 - 42
  • [8] Protic pyridinium ionic liquids: Synthesis, acidity determination and their performances for acid catalysis
    Duan, ZY
    Gu, YL
    Zhang, J
    Zhu, LY
    Deng, YQ
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 250 (1-2) : 163 - 168
  • [9] Versatile Synthesis of Carbon Materials using Protic Ionic Liquids and Salts as Precursors
    Zhang, Wei
    Zhang, Yan
    Ni, Wenpeng P.
    Zhang, Shiguo G.
    CHEMICAL RECORD, 2023, 23 (08):
  • [10] Solvation of Inorganic Nitrate Salts in Protic Ionic Liquids
    Hayes, Robert
    Bernard, Stephen A.
    Imberti, Silvia
    Warr, Gregory G.
    Atkin, Rob
    JOURNAL OF PHYSICAL CHEMISTRY C, 2014, 118 (36): : 21215 - 21225
12345