Synthesis and characterization of the Au11 cluster with sterically demanding phosphine ligands by single crystal X-ray diffraction and XPS spectroscopy

被引：23

作者：

Nunokawa, K

Onaka, S

Yamaguchi, T

Ito, T

Watase, S

Nakamoto, M

机构：

[1] Nagoya Inst Technol, Grad Sch Engn, Dept Environm Technol, Showa Ku, Nagoya, Aichi 4668555, Japan

[2] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan

[3] Osaka Municipal Tech Res Inst, Joto Ku, Osaka 5368553, Japan

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 2003年 / 76卷 / 08期

关键词：

D O I：

10.1246/bcsj.76.1601

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new An, I cluster with (m-CF3C6H4)(3)P ligands has been synthesized and characterized by single crystal X-ray and XPS analysis. The cluster has an incomplete icosahedral skeleton similar to known Au11X3(PR3)(7) clusters, but a stronger distortion from the ideal symmetry has been caused by introducing CF3 substituents at a meta-position of each phenyl ring of PR3 ligands.

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页码：1601 / 1602

页数：2

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