Platinum polyoxoniobates

被引：34
作者：
Abramov, P. A. [1 ,2 ]
Vicent, C. [3 ]
Kompankov, N. B. [1 ]
Gushchin, A. L. [1 ,2 ]
Sokolov, M. N. [1 ,2 ]
机构：
[1] Nikolaev Inst Inorgan Chem Sb RAS, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Novosibirsk 630090, Russia
[3] Univ Jaume 1, Serv Cent Instrumentacio Cient, Castellon de La Plana 12071, Spain
来源：
CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 19期
基金：
俄罗斯科学基金会;
关键词：
PHOTOCATALYTIC PROPERTIES; MOLECULAR-STRUCTURE; MASS-SPECTROMETRY; CRYSTAL-STRUCTURE; COMPLEXES; WATER; POLYOXOTUNGSTATE; HETEROPOLYNIOBATES; ELECTROSPRAY; HEXANIOBATE;
D O I：
10.1039/c5cc00315f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of [Nb6O19](8-) with [Pt(OH)(4)(H2O)(2)] upon heating yielded first characterized platinum polyniobates. A dimeric complex [Nb6O19{Pt(OH)(2)}](2)(12-) (1) is produced in a 1 : 1 molar ratio. Increasing the Pt/Nb-6 molar ratio to 1 : 2 yields a mixture of 1 and a sandwich-type complex [Pt(Nb6O19)(2)](12-) (2).
引用
收藏
页码：4021 / 4023
页数：3
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