Platinum polyoxoniobates

被引：35

作者：

Abramov, P. A. ^{[1
,2
]}

Vicent, C. ^{[3
]}

Kompankov, N. B. ^{[1
]}

Gushchin, A. L. ^{[1
,2
]}

Sokolov, M. N. ^{[1
,2
]}

机构：

[1] Nikolaev Inst Inorgan Chem Sb RAS, Novosibirsk 630090, Russia

[2] Novosibirsk State Univ, Novosibirsk 630090, Russia

[3] Univ Jaume 1, Serv Cent Instrumentacio Cient, Castellon de La Plana 12071, Spain

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 19期

基金：

俄罗斯科学基金会;

关键词：

PHOTOCATALYTIC PROPERTIES; MOLECULAR-STRUCTURE; MASS-SPECTROMETRY; CRYSTAL-STRUCTURE; COMPLEXES; WATER; POLYOXOTUNGSTATE; HETEROPOLYNIOBATES; ELECTROSPRAY; HEXANIOBATE;

D O I：

10.1039/c5cc00315f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [Nb6O19](8-) with [Pt(OH)(4)(H2O)(2)] upon heating yielded first characterized platinum polyniobates. A dimeric complex [Nb6O19{Pt(OH)(2)}](2)(12-) (1) is produced in a 1 : 1 molar ratio. Increasing the Pt/Nb-6 molar ratio to 1 : 2 yields a mixture of 1 and a sandwich-type complex [Pt(Nb6O19)(2)](12-) (2).

引用

页码：4021 / 4023

页数：3

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