Visible-Light-Initiated Cross-Dehydrogenative Coupling of Quinoxalin-2(1H)-ones and Simple Amides with Air as an Oxidant

被引：81
作者：
Xie, Long -Yong [1 ]
Hu, Jia-Li [1 ]
Song, Yan-Xi [1 ]
Jia, Guo-Kai [1 ]
Lin, Ying-Wu [3 ]
He, Jun-Yi [2 ]
Cao, Zhong [2 ]
He, Wei-Min [1 ]
机构：
[1] Hunan Univ Sci & Engn, Dept Chem, Yangzi Tang Rd 130, Yongzhou 425100, Peoples R China
[2] Changsha Univ Sci & Technol, Hunan Prov Key Lab Mat Protect Elect Power & Tran, Wanjiali Rd 960, Changsha 410114, Hunan, Peoples R China
[3] Univ South China, Sch Chem & Chem Engn, Changshen Rd 28, Hengyang 421001, Peoples R China
来源：
ACS SUSTAINABLE CHEMISTRY & ENGINEERING | 2019年 / 7卷 / 24期
关键词：
quinoxalin-2(1H)-ones; amidation; visible-light catalysis; ambient air; metal free; ARYLATION; QUINOXALIN-2(H)-ONES; TRIFLUOROMETHYLATION; PHOSPHONATION; CYCLIZATION; PHOTOREDOX; ALKYLATION; AMINATION; SALTS;
D O I：
10.1021/acssuschemeng.9b05715
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
By using ambient air as an oxidant, various N-acylated 3-aminoquinoxalin-2(1H)-ones were efficiently synthesized through visible-light-promoted rhodamine B-catalyzed amidation reaction of quinoxalin-2(1H)-ones and amides under metal-free and strong oxidant-free conditions.
引用
收藏
页码：19993 / +
页数：13
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