Synthesis of uniform polycrystalline tin dioxide nanofibers and electrochemical application in lithium-ion batteries

被引：63

作者：

Yang, Zunxian ^{[1
,2
,3
,4
,5
]}

Du, Guodong ^{[4
]}

Feng, Chuanqi ^{[4
,6
]}

Li, Sean ^{[7
]}

Chen, Zhixin ^{[1
]}

Zhang, Peng ^{[4
]}

Guo, Zaiping ^{[1
,4
]}

Yu, Xuebin ^{[4
,8
]}

Chen, Guonan ^{[5
]}

Huang, Shizhen ^{[2
,3
]}

Liu, Huakun ^{[4
]}

机构：

[1] Univ Wollongong, Sch Mech Mat & Mechatron Engn, Wollongong, NSW 2522, Australia

[2] Fuzhou Univ, Dept Elect Sci & Technol, Fuzhou 350108, Peoples R China

[3] Fuzhou Univ, Key Lab Microelect & Integrated Circuits Fujian P, Fuzhou 350108, Peoples R China

[4] Univ Wollongong, Inst Superconduct & Elect Mat, Wollongong, NSW 2522, Australia

[5] Fuzhou Univ, Minist Educ, Key Lab Anal & Detect Technol Food Safety, Fuzhou 350002, Peoples R China

[6] Hubei Univ, Coll Chem & Chem Engn, Wuhan 430062, Peoples R China

[7] Univ New S Wales, Sch Mat Sci & Engn, Sydney, NSW 2052, Australia

[8] Fudan Univ, Dept Mat Sci, Shanghai 200433, Peoples R China

来源：

ELECTROCHIMICA ACTA | 2010年 / 55卷 / 19期

基金：

澳大利亚研究理事会;

关键词：

Tin dioxide; Nanofibers; Polycrystalline; Electrospinning; Electrochemical; ANODE MATERIALS; STRUCTURAL-CHARACTERIZATION; NANOCRYSTALLINE SNO2; STORAGE PROPERTIES; CARBON; FABRICATION; NANOTUBES; MICROSPHERES; NANOPOWDERS; NANOWIRES;

D O I：

10.1016/j.electacta.2010.04.045

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

Under optimized synthesis conditions, very large area uniform SnO2 nanofibers consisting of orderly bonded nanoparticles have been obtained for the first time by thermal pyrolysis and oxidization of electrospun tin(II)2-ethylhexanoate/polyacrylonitrile (PAN) polymer nanofibers in air. The structure and morphology were elaborated by X-ray diffraction (XRD), transmission electron microscopy (TEM), and Xray photoelectron spectroscopy (XPS). The SnO2 nanofibers delivered a reversible capacity of 446 mAh g(-1) after 50 cycles at the 100 mA g(-1) rate and excellent rate capability of 477.7 mAh g(-1) at 10.0C. Owing to the improved electrochemical performance, this electrospun SnO2 nanofiber could be one of the most promising candidate anode materials for the lithium-ion battery. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：5485 / 5491

页数：7

共 32 条

[1] Structural characterization of nanocrystalline SnO2 by X-ray and Raman spectroscopy [J].

Abello, L ;

Bochu, B ;

Gaskov, A ;

Koudryavtseva, S ;

Lucazeau, G ;

Roumyantseva, M .

JOURNAL OF SOLID STATE CHEMISTRY, 1998, 135 (01) :78-85

[2] A Computational Study on Adsorption Configurations and Dissociative Reactions of the HN3 Molecule on the TiO2 Anatase (101) Surface [J].

Chang, Jee-Gong ;

Ju, Shin-Pon ;

Chang, Ching-Sheng .

JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (46) :18017-18027

[3] Electrochemical behavior of nanocrystalline tin oxide electrodeposited on a Cu substrate for Li-ion batteries [J].

Chang, ST ;

Leu, IC ;

Liao, CL ;

Yen, JH ;

Hon, MH .

JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (12) :1821-1826

[4] Modification of polyacrylonitrile (PAN) carbon fiber precursor via post-spinning plasticization and stretching in dimethyl formamide (DMF) [J].

Chen, JC ;

Harrison, IR .

CARBON, 2002, 40 (01) :25-45

[5] Fabrication of Polycrystalline ZnO Nanotubes from the Electrospinning of Zn2+/Poly(acrylic acid) [J].

Chen, Wen-Shiang ;

Huang, De-An ;

Chen, Hung-Cheng ;

Shie, Tzung-Ying ;

Hsieh, Chi-Hsiang ;

Liao, Jiunn-Der ;

Kuo, Changshu .

CRYSTAL GROWTH & DESIGN, 2009, 9 (09) :4070-4077

[6] Facile one-pot synthesis of mesoporous SnO2 microspheres via nanoparticles assembly and lithium storage properties [J].

Demir-Cakan, Rezan ;

Hu, Yong-Sheng ;

Antonietti, Markus ;

Maier, Joachim ;

Titirici, Maria-Magdalena .

CHEMISTRY OF MATERIALS, 2008, 20 (04) :1227-1229

[7] Synthesis of polycrystalline SnO2 nanotubes on carbon nanotube template for anode material of lithium-ion battery [J].

Du, Ning ;

Zhang, Hui ;

Chen, Bindi ;

Ma, Xiangyang ;

Huang, Xiaohua ;

Tu, Jiangping ;

Yang, Deren .

MATERIALS RESEARCH BULLETIN, 2009, 44 (01) :211-215

[8] Electrochemical reduction of nano-SiO2 in hard carbon as anode material for lithium ion batteries [J].

Guo, Bingkun ;

Shu, Jie ;

Wang, Zhaoxiang ;

Yang, Hong ;

Shi, Lihong ;

Liu, Yinong ;

Chen, Liquan .

ELECTROCHEMISTRY COMMUNICATIONS, 2008, 10 (12) :1876-1878

[9] Ultra-fine porous SnO2 nanopowder prepared via a molten salt process: a highly efficient anode material for lithium-ion batteries [J].

Guo, Zai Ping ;

Du, Guo Dong ;

Nuli, Yanna ;

Hassan, Mohd Faiz ;

Liu, Hua Kun .

JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (20) :3253-3257

[10]

Hulicová D, 2002, ADV MATER, V14, P452, DOI 10.1002/1521-4095(20020318)14:6<452::AID-ADMA452>3.0.CO

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