{Tc(NO)(Cp)(PPh3)}+ - a novel technetium(I) core

被引：15

作者：

Ackermann, J. ^{[1
]}

Hagenbach, A. ^{[1
]}

Abram, U. ^{[1
]}

机构：

[1] Free Univ Berlin, Inst Chem & Biochem, Fabeckstr 34-36, D-14195 Berlin, Germany

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 67期

关键词：

RAY STRUCTURAL-ANALYSIS; ORGANOMETALLIC COMPOUNDS; CRYSTAL-STRUCTURE; RHENIUM; COMPLEXES; CHEMISTRY; METAL; RE; TRIS(CYCLOPENTADIENYL)TECHNETIUM(III); RADIOMETALS;

D O I：

10.1039/c6cc05811f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions between [TcI(NO)X-2(PPh3)(2)(CH3CN)] complexes (X = Cl, Br) and KCp form the pseudotetrahedral organotechnetium compounds [TcI(NO)(Cp)(PPh3)X]. The halide ligands can readily be replaced by other halides or organometallic ligands giving access to a novel family of technetium(I) compounds with the robust {Tc(NO)(Cp)(PPh3)}(+) core.

引用

页码：10285 / 10288

页数：4

共 55 条

[1] Technetium and rhenium - Coordination chemistry and nuclear medical applications [J].

Abram, Ulrich ;

Alberto, Roger .

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2006, 17 (08) :1486-1500

[2]

Ackermann J., 2014, Inorg. Chim. Acta, V419, P59, DOI [10.1016/j.ica.2014.04.032, DOI 10.1016/J.ICA.2014.04.032]

[3]

Agbossou F., 1992, INORG SYNTH, V29, P211

[4] SYNTHESIS, STRUCTURE, AND REACTIVITY OF THE CHIRAL RHENIUM PHENYL COMPLEX (ETA-5-C5H5)RE(NO)(PPH3)(C6H5) [J].

AGBOSSOU, SK ;

BODNER, GS ;

PATTON, AT ;

GLADYSZ, JA .

ORGANOMETALLICS, 1990, 9 (04) :1184-1191

[5] Steps towards [(C5Me5)TcO3]:: Novel synthesis of [(C5Me5)Tc(CO)3] from [{Tc(μ3-OH)(CO)3}4] and oxidation of [(C5Me5)M(CO)3] (M = Tc, Re) with Br2 [J].

Alberto, R ;

Schibli, R ;

Egli, A ;

Abram, U ;

Abram, S ;

Kaden, TA ;

Schubiger, PA .

POLYHEDRON, 1998, 17 (07) :1133-1140

[6]

Alberto R, 1999, COORDIN CHEM REV, V190, P901

[7]

Alberto R., 2011, HDB NUCL CHEM, P2073, DOI 10.1007/978-1-4419-0720-2_43

[8] Organometallic Radiopharmaceuticals [J].

Alberto, Roger .

MEDICINAL ORGANOMETALLIC CHEMISTRY, 2010, 32 :219-246

[9] ORGANOMETALLIC CHEMISTRY OF TECHNETIUM .7. X-RAY STRUCTURE-ANALYSIS OF TRIS(CYCLOPENTADIENYL)TECHNETIUM(III), (ETA(5)-C5H5)2TC(ETA(1)-C5H5) - DIPOLE FEATURES AND CHARGE-DISTRIBUTION OF THE SPECIES (C5H5)3M (M=V, TC, RE) [J].

APOSTOLIDIS, C ;

KANELLAKOPULOS, B ;

MAIER, R ;

REBIZANT, J ;

ZIEGLER, ML .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 411 (1-2) :171-179

[10] BIS(CYCLOPENTADIENYL)TECHNETIUM(III) CHLORIDE AND TRIS(CYCLOPENTADIENYL)TECHNETIUM(III), NEW ORGANOMETALLIC COMPOUNDS OF TRIVALENT TECHNETIUM [J].

APOSTOLIDIS, C ;

KANELLAKOPULOS, B ;

MAIER, R ;

REBIZANT, J ;

ZIEGLER, ML .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 396 (2-3) :315-326

← 1 2 3 4 5 6 →