Raman-active wurtzite CdO nanophase and phonon signatures in CdO/ZnO heterostructures fabricated by nonequilibrium laser plasma ablation and stress control

被引:39
作者
Ashrafi, Almamun [1 ]
Ostrikov, Kostya [2 ,3 ]
机构
[1] Univ Vermont, Dept Phys, Burlington, VT 05405 USA
[2] Univ Sydney, Sch Phys, Sydney, NSW 2006, Australia
[3] CSIRO Mat Sci & Engn, PNCA, Lindfield, NSW 2070, Australia
关键词
MICROCRYSTALS; SCATTERING; NANOWIRES;
D O I
10.1063/1.3573795
中图分类号
O59 [应用物理学];
学科分类号
摘要
A combination of laser plasma ablation and strain control in CdO/ZnO heterostructures is used to produce and stabilize a metastable wurtzite CdO nanophase. According to the Raman selection rules, this nanophase is Raman-active whereas the thermodynamically preferred rocksalt phase is inactive. The wurtzite-specific and thickness/strain-dependent Raman fingerprints and phonon modes are identified and can be used for reliable and inexpensive nanophase detection. The wurtzite nanophase formation is also confirmed by x-ray diffractometry. The demonstrated ability of the metastable phase and phonon mode control in CdO/ZnO heterostructures is promising for the development of next-generation light emitting sources and exciton-based laser diodes. (C) 2011 American Institute of Physics. [doi:10.1063/1.3573795]
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页数:3
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共 16 条
[1]   Micro-Raman investigation of optical phonons in ZnO nanocrystals [J].
Alim, KA ;
Fonoberov, VA ;
Shamsa, M ;
Balandin, AA .
JOURNAL OF APPLIED PHYSICS, 2005, 97 (12)
[2]   Spontaneous Growth of Superstructure α-Fe2O3 Nanowire and Nanobelt Arrays in Reactive Oxygen Plasma [J].
Cvelbar, Uros ;
Chen, Zhiqiang ;
Sunkara, Mahendra K. ;
Mozetic, Miran .
SMALL, 2008, 4 (10) :1610-1614
[3]   Reactive oxygen plasma-enabled synthesis of nanostructured CdO: tailoring nanostructures through plasma-surface interactions [J].
Cvelbar, Uros ;
Ostrikov, Kostya ;
Mozetic, Miran .
NANOTECHNOLOGY, 2008, 19 (40)
[4]   A first-principle analysis on the phase stabilities, chemical bonds and band gaps of wurtzite structure AxZn1-xO alloys (A = Ca, Cd, Mg) [J].
Fan, X. F. ;
Sun, H. D. ;
Shen, Z. X. ;
Kuo, Jer-Lai ;
Lu, Y. M. .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2008, 20 (23)
[5]   Self-organized nanostructures on atmospheric microplasma exposed surfaces [J].
Mariotti, Davide ;
Svrcek, Vladimir ;
Kim, Dae-Gun .
APPLIED PHYSICS LETTERS, 2007, 91 (18)
[6]   Colloquium:: Reactive plasmas as a versatile nanofabrication tool [J].
Ostrikov, K .
REVIEWS OF MODERN PHYSICS, 2005, 77 (02) :489-511
[7]   The promise and perils of wide-bandgap semiconductor nanowires for sensing, electronic, and photonic applications [J].
Pearton, Stephen J. ;
Norton, David P. ;
Ren, Fan .
SMALL, 2007, 3 (07) :1144-1150
[8]   INFRARED AND RAMAN-SPECTRA OF CDO [J].
POPOVIC, ZV ;
STANISIC, G ;
STOJANOVIC, D ;
KOSTIC, R .
PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 1991, 165 (02) :K109-K112
[9]   INFRARED-ABSORPTION BY COUPLED SURFACE-PHONON SURFACE-PLASMON MODES IN MICROCRYSTALS OF CDO [J].
RIEDER, KH ;
ISHIGAME, M ;
GENZEL, L .
PHYSICAL REVIEW B-SOLID STATE, 1972, 6 (10) :3804-+
[10]   Hexagonal nanodisks of cadmium hydroxide and oxide with nanoporous structure [J].
Shi, WD ;
Wang, C ;
Wang, HS ;
Zhang, HJ .
CRYSTAL GROWTH & DESIGN, 2006, 6 (04) :915-918