Equilibrium and Thermodynamic Studies on the Removal and Recovery of Safranine-T Dye from Industrial Effluents

被引:74
|
作者
Gupta, Vinod K. [1 ,2 ]
Jain, Rajeev [3 ]
Saleh, T. A. [2 ]
Nayak, A. [1 ]
Malathi, S. [3 ]
Agarwal, Shilpi [3 ]
机构
[1] Indian Inst Technol Roorkee, Dept Chem, Roorkee 247667, Uttar Pradesh, India
[2] King Fahd Univ Petr & Minerals, Dept Chem, Dhahran 31261, Saudi Arabia
[3] Jiwaji Univ, Sch Studies Chem, Gwalior 474011, India
关键词
adsorption; deoiled-mustard; desorption; Safranine-T; LOW-COST ADSORBENTS; BAGASSE FLY-ASH; DE-OILED-SOYA; WASTE-WATER; AQUEOUS-SOLUTIONS; BOTTOM ASH; RED MUD; ACTIVATED CARBONS; TEXTILE EFFLUENT; METHYLENE-BLUE;
D O I
10.1080/01496395.2010.535591
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this study, deoiled-mustard obtained from local oil mills has been used as an inexpensive and effective adsorbent for the removal of Safranine-T dye from wastewater. The influence of various factors on the adsorption capacity has been studied by batch experiments. The adsorption studies revealed that the ongoing adsorption validates Langmuir adsorption isotherms better than the Freundlich adsorption isotherm at temperatures 40, 50, 60 degrees C. Thermodynamic parameters such as G degrees, H degrees, and S degrees for the adsorption process were calculated. Desorption profile revealed that a significant portion (83%) of the dye could be desorbed by using 12% acetic acid solution as an eluting agent. A comparative analysis of the adsorption capacities of various adsorbents reveals the superior performance of the adsorbent under study. The results indicated that deoiled-mustard is a good and low-cost adsorbent from the practical point of view for dyes removal and can be used as an economically viable alternative to commercial activated carbon.
引用
收藏
页码:839 / 846
页数:8
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