SYNTHESIS AND THERMAL PROPERTIES OF TWO NEW DICATIONIC IONIC LIQUIDS

被引：5

作者：

Claros, Martha ^{[1
]}

Graber, Teofilo A. ^{[1
]}

Brito, Ivan ^{[2
]}

Albanez, Joselyn ^{[2
]}

Gavin, Jose A. ^{[3
]}

机构：

[1] Univ Antofagasta, CICITEM, Fac Ingn, Dept Ingn Quim, Antofagasta, Chile

[2] Univ Antofagasta, CICITEM, Fac Ciencias Basicas, Dept Quim, Antofagasta, Chile

[3] Univ La Laguna, Inst Univ Bioorgan Antonio Gonzalez, E-38206 Tenerife, Spain

来源：

JOURNAL OF THE CHILEAN CHEMICAL SOCIETY | 2010年 / 55卷 / 03期

关键词：

Dicationic Ionic liquids; thermal properties; synthesis; IMIDAZOLIUM; SOLVENTS;

D O I：

10.4067/S0717-97072010000300027

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new dicationic ionic liquids 1,7-bis(3-methylimidazolium-1-yl)heptane bromide (1) and 1,8-bis(3-methylimidazolium-1-yl)octane bromide (II) have been synthesized and characterized by elemental analysis, FT-IR, H-1 and C-13 NMR, and TG-DSC techniques. The compound (1) is liquid at room temperature, whereas (II) is liquid at 42.7 degrees C.

引用

页码：396 / 398

页数：3

共 20 条

[1] Structure and properties of high stability geminal dicationic ionic liquids [J].

Anderson, JL ;

Ding, RF ;

Ellern, A ;

Armstrong, DW .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (02) :593-604

[2] Synthesis and properties of ionic liquid-type Gemini imidazolium surfactants [J].

Ao, Mingqi ;

Xu, Guiying ;

Zhu, Yanyan ;

Bai, Yan .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2008, 326 (02) :490-495

[3] Interfacial and micellar properties of imidazolium-based monocationic and dicationic ionic liquids [J].

Baltazar, Quinner Q. ;

Chandawalla, Janaki ;

Sawyer, Keahna ;

Anderson, Jared L. .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2007, 302 (1-3) :150-156

[4] Synthesis, characterization and properties of geminal imidazolium ionic liquids [J].

Ding, Yun-Sheng ;

Zha, Min ;

Zhang, Jun ;

Wang, Seng-Shan .

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2007, 298 (03) :201-205

[5] Ionic liquids. Green solvents for the future [J].

Earle, MJ ;

Seddon, KR .

PURE AND APPLIED CHEMISTRY, 2000, 72 (07) :1391-1398

[6] Using geminal dicationic ionic liquids as solvents for high-temperature organic reactions [J].

Han, XX ;

Armstrong, DW .

ORGANIC LETTERS, 2005, 7 (19) :4205-4208

[7] The phase behaviour of 1-alkyl-3-methylimidazolium tetrafluoroborates; ionic liquids and ionic liquid crystals [J].

Holbrey, JD ;

Seddon, KR .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (13) :2133-2139

[8] PEG-linked geminal dicationic ionic liquids as selective, high-stability gas chromatographic stationary phases [J].

Huang, Ke ;

Han, Xinxin ;

Zhang, Xiaotong ;

Armstrong, Daniel W. .

ANALYTICAL AND BIOANALYTICAL CHEMISTRY, 2007, 389 (7-8) :2265-2275

[9] Polyethylene glycol functionalized dicationic ionic liquids with alkyl or polyfluoroalkyl substituents as high temperature lubricants [J].

Jin, CM ;

Ye, CF ;

Phillips, BS ;

Zabinski, JS ;

Liu, XQ ;

Liu, WM ;

Shreeve, JM .

JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (16) :1529-1535

[10] Novel thixotropic gel electrolytes based on dicationic bis-imidazolium salts for quasi-solid-state dye-sensitized solar cells [J].

Kim, Jun Young ;

Kim, Tae Ho ;

Kim, Dong Young ;

Park, Narn-Gyu ;

Ahn, Kwang-Duk .

JOURNAL OF POWER SOURCES, 2008, 175 (01) :692-697

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