Phase Dependent Heterogeneous Dynamics of Li+ Ion in LiPO3 Based Systems

被引：7
|
作者：
Money, Benson K. [1 ]
Hariharan, K. [1 ]
机构：
[1] Indian Inst Technol Madras, Dept Phys, Solid State Ion Lab, Madras 600036, Tamil Nadu, India
来源：
INTEGRATED FERROELECTRICS | 2010年 / 120卷
关键词：
Ion dynamics; polycrystalline; composite electrolytes; glass; polymer; POLYMER ELECTROLYTES; COMPUTER-SIMULATION; CONDUCTORS; TRANSPORT; GLASSES; CONDUCTIVITY; NMR;
D O I：
10.1080/10584587.2010.491729
中图分类号：
TM [电工技术]; TN [电子技术、通信技术];
学科分类号：
0808 ; 0809 ;
摘要：
A normal lithium ion conductor, lithium metaphosphate has been taken up for transport studies, as it has enabled for investigation of the Li+ ion transport in (i) crystalline form as LiPO3, (ii) crystalline LiPO3 heterogeneously doped with inert oxide inclusion and homogeneously doped with aliovalent cations, (iii) glassy form as mol% 50Li(2)O:50P(2)O(5), synthesized by melt-quenching process and (iv) newly identified polymer-metal salt complex (PEO)(6):LiPO3. All the above materials have been characterized through XRD, DSC, SEM, Raman spectroscopy and impedance spectroscopy techniques.
引用
收藏
页码：75 / 89
页数：15
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