Sulfur@metal cotton with superior cycling stability as cathode materials for rechargeable lithium-sulfur batteries

被引：29

作者：

Zhang, J. X. ^{[1
,2
]}

Ma, Z. S. ^{[1
,2
]}

Cheng, J. J. ^{[1
,2
]}

Wang, Yan ^{[3
]}

Wu, C. ^{[1
,2
]}

Pan, Y. ^{[1
,2
]}

Lu, C. ^{[4
]}

机构：

[1] Xiangtan Univ, Key Lab Low Dimens Mat & Applicat Technol, Minist Educ, Xiangtan 411105, Hunan, Peoples R China

[2] Xiangtan Univ, Sch Mat Sci & Engn, Xiangtan 411105, Hunan, Peoples R China

[3] Hunan Univ Sci & Technol, Sch Informat & Elect Engn, Xiangtan 411201, Hunan, Peoples R China

[4] Curtin Univ, Dept Mech Engn, Perth, WA 6845, Australia

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2015年 / 738卷

基金：

国家高技术研究发展计划(863计划); 中国国家自然科学基金;

关键词：

Li-S battery; Metal cotton; Cathode; Electrochemistry; PERFORMANCE; COMPOSITE; ELECTRODE; OXIDE;

D O I：

10.1016/j.jelechem.2014.12.003

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Lithium-sulfur (Li-S) batteries have great potential for some high energy applications such as electric vehicles and smart grids due to the high capacity, natural abundance, low cost and environmental friendliness of sulfur. In this work, we use the metal cotton to absorb sulfur firmly as cathode material for Li-S batteries. The as-designed sulfur@metal cotton (S@MC) composite shows a good cycling stability and rate capability. The capacity is retained at 480 mA h g(-1) at 0.1 C after 200 cycles. Furthermore, for higher rates, the S@MC cathode material also exhibits stable capacity during different periods. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：184 / 187

页数：4

共 25 条

[1] Confine sulfur in mesoporous metal-organic framework @ reduced graphene oxide for lithium sulfur battery [J].

Bao, Weizhai ;

Zhang, Zhian ;

Qu, Yaohui ;

Zhou, Chengkun ;

Wang, Xiwen ;

Li, Jie .

JOURNAL OF ALLOYS AND COMPOUNDS, 2014, 582 :334-340

[2]

Bruce PG, 2012, NAT MATER, V11, P19, DOI [10.1038/nmat3191, 10.1038/NMAT3191]

[3] Hybrid network CuS monolith cathode materials synthesized via facile in situ melt-diffusion for Li-ion batteries [J].

Cheng, Juanjuan ;

Pan, Yong ;

Zhu, Jingtao ;

Li, Zhenzhen ;

Pan, Junan ;

Ma, Zengsheng .

JOURNAL OF POWER SOURCES, 2014, 257 :192-197

[4] Lithium-sulfur batteries with superior cycle stability by employing porous current collectors [J].

Chung, Sheng-Heng ;

Manthiram, Arumugam .

ELECTROCHIMICA ACTA, 2013, 107 :569-576

[5] New Approaches for High Energy Density Lithium-Sulfur Battery Cathodes [J].

Evers, Scott ;

Nazar, Linda F. .

ACCOUNTS OF CHEMICAL RESEARCH, 2013, 46 (05) :1135-1143

[6] Multi-electron reaction materials for high energy density batteries [J].

Gao, Xue-Ping ;

Yang, Han-Xi .

ENERGY & ENVIRONMENTAL SCIENCE, 2010, 3 (02) :174-189

[7] A High-Performance Polymer Tin Sulfur Lithium Ion Battery [J].

Hassoun, Jusef ;

Scrosati, Bruno .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (13) :2371-2374

[8] Ionic shield for polysulfides towards highly-stable lithium-sulfur batteries [J].

Huang, Jia-Qi ;

Zhang, Qiang ;

Peng, Hong-Jie ;

Liu, Xin-Yan ;

Qian, Wei-Zhong ;

Wei, Fei .

ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (01) :347-353

[9] Advances in Li-S batteries [J].

Ji, Xiulei ;

Nazar, Linda F. .

JOURNAL OF MATERIALS CHEMISTRY, 2010, 20 (44) :9821-9826

[10] Advanced amorphous nanoporous stannous oxide composite with carbon nanotubes as anode materials for lithium-ion batteries [J].

Jiang, Wenjuan ;

Zeng, Weiyao ;

Ma, Zengsheng ;

Pan, Yong ;

Lin, Jianguo ;

Lu, Chunsheng .

RSC ADVANCES, 2014, 4 (78) :41281-41286

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