A convenient synthesis of the side-chain of sterols

被引：11

作者：

Schmittberger, T ^{[1
]}

Uguen, D ^{[1
]}

机构：

[1] ECOLE EUROPEENNE HAUTES ETUD IND CHIM,CNRS,ORGAN SYNTH LAB,F-67008 STRASBOURG,FRANCE

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 01期

关键词：

D O I：

10.1016/0040-4039(95)02075-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Potassium t-butoxide-induced Ramberg-Backlund rearrangement of chlorosulfones formed from a cyclopregnane-20-thiomethanol derivative has been shown to give Delta(22)-unsaturated steroids with high trans stereoselectivity.

引用

页码：29 / 32

页数：4

共 50 条

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