Gas-phase pyrolysis of N-alkoxyphthalimides to functionally substituted aldehydes: kinetic and mechanistic study

被引：7
作者：
Al-Etaibi, Alya M. [1 ]
Al-Awadi, Nouria A. [2 ]
Ibrahim, Maher R. [2 ]
Ibrahim, Yehia A. [2 ]
机构：
[1] Publ Author Appl Educ & Training, Coll Hlth Sci, Dept Nat Sci, Kuwait, Kuwait
[2] Kuwait Univ, Fac Sci, Dept Chem, Safat 13060, Kuwait
来源：
ARKIVOC | 2010年
关键词：
FVP; N-alkoxyphthalimides; aldehydes; kinetics; reaction mechanism; SULFONYL HYDRAZONES; PART; ALPHA; ACIDS; ELIMINATION; THERMOLYSIS; REACTIVITY; OXIMES; ESTERS;
D O I：
10.3998/ark.5550190.0011.a13
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Flash vacuum Pyrolysis (FVP) of primary N-alkoxyphthalimides at 400-500 degrees C and 0.02 Torr gave functionally substituted aldehydes. A mechanism of this pyrolytic transformation was proposed based on the kinetic data and product analysis.
引用
收藏
页码：149 / 162
页数：14
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