Cysteamine-capped copper nanoclusters as a highly selective turn-on fluorescent assay for the detection of aluminum ions

被引：51

作者：

Boonmee, Chanida ^{[1
,2
]}

Promarak, Vinich ^{[3
]}

Tuntulani, Thawatchai ^{[4
]}

Ngeontae, Wittaya ^{[1
,2
]}

机构：

[1] Khon Kaen Univ, Dept Chem, Mat Chem Res Ctr, Khon Kaen 40002, Thailand

[2] Khon Kaen Univ, Ctr Excellence Innovat Chem, Fac Sci, Khon Kaen 40002, Thailand

[3] Vidyasirimedhi Inst Sci & Technol, Sch Mol Sci & Engn, Wang Chan 21210, Rayong, Thailand

[4] Chulalongkorn Univ, Dept Chem, Fac Sci, Bangkok 10330, Thailand

来源：

TALANTA | 2018年 / 178卷

关键词：

Copper nanoclusters; Chemical sensor; Fluorescent sensor; Metal nanoclusters; Nanoparticles; Optical nanomaterials; AGGREGATION-INDUCED EMISSION; ONE-STEP SYNTHESIS; QUANTUM DOTS; CU NANOCLUSTERS; PROBE; SENSOR; CHEMOSENSOR; SIZE; AL3+; AG+;

D O I：

10.1016/j.talanta.2017.10.006

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A new type of copper nanoclusters was synthesized by a one-pot reaction using cysteamine as a capping agent and reducing agent (Cys-CuNCs). The synthesized CuNCs exhibited a spherical shape and a monodisperse and strong fluorescent emission characteristic peak at 430 nm when exciting at 330 nm. The Cys-CuNCs were demonstrated as a fluorescent chemodosimeter for the selective detection of Al3+ In the presence of Al3+, the fluorescent emission of the Cys-CuNCs was considerably enhanced, while other studied metal ions did not show this phenomenon. The fluorescent intensity near 380 nm linearly increased with an increasing Al3+ concentration. The proposed method provided a working range of 1-7 mu M with a low detection limit of 26.7 nM and was applied to determine Al3+ in drinking water samples with satisfactory results.

引用

页码：796 / 804

页数：9

共 41 条

[1] Optical fibre Al(III) sensor based on solid surface fluorescence measurement [J].

Ahmad, M ;

Narayanaswamy, R .

SENSORS AND ACTUATORS B-CHEMICAL, 2002, 81 (2-3) :259-266

[2] Quantum dots as cellular probes [J].

Alivisatos, AP ;

Gu, WW ;

Larabell, C .

ANNUAL REVIEW OF BIOMEDICAL ENGINEERING, 2005, 7 :55-76

[3] Synthesis and characterization of a new organic nanoparticle as fluorescent chemosensor for aluminum ions [J].

Azadbakht, Reza ;

Talebi, Mohammad ;

Karimi, Javad ;

Golbedaghi, Reza .

INORGANICA CHIMICA ACTA, 2016, 453 :728-734

[4] Experimental design optimization for the ICP-AES determination of Li, Na, K, Al, Fe, Mn and Zn in human serum [J].

Bianchi, F. ;

Maffini, M. ;

Mangia, A. ;

Marengo, E. ;

Mucchino, C. .

JOURNAL OF PHARMACEUTICAL AND BIOMEDICAL ANALYSIS, 2007, 43 (02) :659-665

[5] Copper nanoclusters as a highly sensitive and selective fluorescence sensor for ferric ions in serum and living cells by imaging [J].

Cao, Haiyan ;

Chen, Zhaohui ;

Zheng, Huzhi ;

Huang, Yuming .

BIOSENSORS & BIOELECTRONICS, 2014, 62 :189-195

[6] Luminescent quantum dots for multiplexed biological detection and imaging [J].

Chan, WCW ;

Maxwell, DJ ;

Gao, XH ;

Bailey, RE ;

Han, MY ;

Nie, SM .

CURRENT OPINION IN BIOTECHNOLOGY, 2002, 13 (01) :40-46

[7] Selective colorimetric detection of polynucleotides based on the distance-dependent optical properties of gold nanoparticles [J].

Elghanian, R ;

Storhoff, JJ ;

Mucic, RC ;

Letsinger, RL ;

Mirkin, CA .

SCIENCE, 1997, 277 (5329) :1078-1081

[8] Aluminium as a risk factor in Alzheimer's disease, with emphasis on drinking water [J].

Flaten, TP .

BRAIN RESEARCH BULLETIN, 2001, 55 (02) :187-196

[9] Copper nanocluster-based fluorescent sensors for sensitive and selective detection of kojic acid in food stuff [J].

Gao, Zhao ;

Su, Rongxin ;

Qi, Wei ;

Wang, Libing ;

He, Zhimin .

SENSORS AND ACTUATORS B-CHEMICAL, 2014, 195 :359-364

[10] Aluminum(III) selective potentiometric sensor based on morin in poly(vinyl chloride) matrix [J].

Gupta, Vinod K. ;

Jain, Ajay K. ;

Maheshwari, Gaurav .

TALANTA, 2007, 72 (04) :1469-1473

← 1 2 3 4 5 →