Ru/Cu Photoredox or Cu/Ag Catalyzed C4-H Sulfonylation of 1-Naphthylamides at Room Temperature

被引：68

作者：

Bai, Peirong ^{[1
]}

Sun, Suyan ^{[1
]}

Li, Zexian ^{[1
]}

Qiao, Huijie ^{[1
]}

Su, Xiaoxue ^{[1
]}

Yang, Fan ^{[1
]}

Wu, Yusheng ^{[2
,3
]}

Wu, Yangjie ^{[1
]}

机构：

[1] Zhengzhou Univ, Coll Chem & Mol Engn, Henan Key Lab Chem Biol & Organ Chem, Key Lab Appl Chem Henan Univ, Zhengzhou 450052, Henan, Peoples R China

[2] Tetranov Biopharm LLC, Zhengzhou 450052, Henan, Peoples R China

[3] Collaborat Innovat Ctr New Drug Res & Safety Eval, Zhengzhou 450052, Henan, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2017年 / 82卷 / 23期

基金：

中国国家自然科学基金;

关键词：

C-H FUNCTIONALIZATION; TRANSITION-METAL CATALYSIS; BOND FUNCTIONALIZATION; ARYLSULFONYL CHLORIDES; DIRECTED C(SP(2))-H; CARBOXYLIC-ACIDS; SODIUM; DERIVATIVES; AMINOQUINOLINES; PHOSPHONATION;

D O I：

10.1021/acs.joc.7b01917

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A mild and efficient protocol for C4-H sulfonylation of 1-naphthylamine derivatives with sodium sulfinates has been described. This C4 sulfonylation proceeded smoothly at room temperature under Ru/Cu photoredox catalysis or Cu/Ag cocatalysis and could tolerate various functional groups. In addition, control experiments suggested that this C4-H sulfonylation reaction might proceed via a single-electron-transfer process.

引用

页码：12119 / 12127

页数：9

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